Sericin as compatibilizer in starch/ polyester blown films
Abstract This study investigated the effects of low concentrations of sericin (≤ 1.5 wt%) in starch- poly(butylene-adipate-co-terephthalate) (PBAT) films. The films were produced by blown extrusion and mechanical, barrier and structural properties were determined. Films containing 1.0 and 1.5 wt% s...
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Associação Brasileira de Polímeros
2018-11-01
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doaj-ee325719e4cb4a049d99cc9b17daf6af2020-11-25T00:46:11ZengAssociação Brasileira de PolímerosPolímeros1678-51692018-11-01010.1590/0104-1428.05117S0104-14282018005006106Sericin as compatibilizer in starch/ polyester blown filmsPatrícia Salomão GarciaFranciele Rezende Barbosa TurbianiAlessandra Machado BaronGuilherme Luiz BrizolaMariane Alves TavaresFabio YamashitaDaniel EirasMaria Victória Eiras GrossmannAbstract This study investigated the effects of low concentrations of sericin (≤ 1.5 wt%) in starch- poly(butylene-adipate-co-terephthalate) (PBAT) films. The films were produced by blown extrusion and mechanical, barrier and structural properties were determined. Films containing 1.0 and 1.5 wt% sericin showed higher tensile strength (6.41 and 6.59 MPa) and Young's modulus (90.88 and 132.71 MPa) compared with film without sericin (4.76 MPa and 18.64 MPa). When 0.5 wt% of sericin was used, the elongation was reduced by 62%. The addition of sericin in a concentration of 1.5% (w/w) decreased the water vapor permeability of films from 7.55 to 5.94 g (m s Pa)-1, likely due to the formation of a more homogeneous and compact matrix. Based on these results, a mechanism of action is proposed, whereby sericin acts at the interface of the polymers (starch and PBAT), reducing the interfacial tension and enhancing compatibility.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282018005006106&lng=en&tlng=enbiodegradable packagingcompatibilizationextrusionpoly(butylene- adipate-co-terephthalate) |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Patrícia Salomão Garcia Franciele Rezende Barbosa Turbiani Alessandra Machado Baron Guilherme Luiz Brizola Mariane Alves Tavares Fabio Yamashita Daniel Eiras Maria Victória Eiras Grossmann |
spellingShingle |
Patrícia Salomão Garcia Franciele Rezende Barbosa Turbiani Alessandra Machado Baron Guilherme Luiz Brizola Mariane Alves Tavares Fabio Yamashita Daniel Eiras Maria Victória Eiras Grossmann Sericin as compatibilizer in starch/ polyester blown films Polímeros biodegradable packaging compatibilization extrusion poly(butylene- adipate-co-terephthalate) |
author_facet |
Patrícia Salomão Garcia Franciele Rezende Barbosa Turbiani Alessandra Machado Baron Guilherme Luiz Brizola Mariane Alves Tavares Fabio Yamashita Daniel Eiras Maria Victória Eiras Grossmann |
author_sort |
Patrícia Salomão Garcia |
title |
Sericin as compatibilizer in starch/ polyester blown films |
title_short |
Sericin as compatibilizer in starch/ polyester blown films |
title_full |
Sericin as compatibilizer in starch/ polyester blown films |
title_fullStr |
Sericin as compatibilizer in starch/ polyester blown films |
title_full_unstemmed |
Sericin as compatibilizer in starch/ polyester blown films |
title_sort |
sericin as compatibilizer in starch/ polyester blown films |
publisher |
Associação Brasileira de Polímeros |
series |
Polímeros |
issn |
1678-5169 |
publishDate |
2018-11-01 |
description |
Abstract This study investigated the effects of low concentrations of sericin (≤ 1.5 wt%) in starch- poly(butylene-adipate-co-terephthalate) (PBAT) films. The films were produced by blown extrusion and mechanical, barrier and structural properties were determined. Films containing 1.0 and 1.5 wt% sericin showed higher tensile strength (6.41 and 6.59 MPa) and Young's modulus (90.88 and 132.71 MPa) compared with film without sericin (4.76 MPa and 18.64 MPa). When 0.5 wt% of sericin was used, the elongation was reduced by 62%. The addition of sericin in a concentration of 1.5% (w/w) decreased the water vapor permeability of films from 7.55 to 5.94 g (m s Pa)-1, likely due to the formation of a more homogeneous and compact matrix. Based on these results, a mechanism of action is proposed, whereby sericin acts at the interface of the polymers (starch and PBAT), reducing the interfacial tension and enhancing compatibility. |
topic |
biodegradable packaging compatibilization extrusion poly(butylene- adipate-co-terephthalate) |
url |
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282018005006106&lng=en&tlng=en |
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