PVDF Fibers Modification by Nitrate Salts Doping

The method of inclusion of various additives into a polymer depends highly on the material in question and the desired effect. In the case of this paper, nitride salts were introduced into polyvinylidene fluoride fibers prepared by electrospinning. The resulting changes in the structural, chemical a...

Full description

Bibliographic Details
Main Authors:	Dinara Sobola, Pavel Kaspar, Klára Částková, Rashid Dallaev, Nikola Papež, Petr Sedlák, Tomáš Trčka, Farid Orudzhev, Jaroslav Kaštyl, Adam Weiser, Alexandr Knápek, Vladimír Holcman
Format:	Article
Language:	English
Published:	MDPI AG 2021-07-01
Series:	Polymers
Subjects:	PVDF nitrate salt XPS XRD Raman spectroscopy FTIR
Online Access:	https://www.mdpi.com/2073-4360/13/15/2439

id	doaj-ee51efe03ee047dd9f3296f62dfe9389
record_format	Article
spelling	doaj-ee51efe03ee047dd9f3296f62dfe93892021-08-06T15:29:47ZengMDPI AGPolymers2073-43602021-07-01132439243910.3390/polym13152439PVDF Fibers Modification by Nitrate Salts DopingDinara Sobola0Pavel Kaspar1Klára Částková2Rashid Dallaev3Nikola Papež4Petr Sedlák5Tomáš Trčka6Farid Orudzhev7Jaroslav Kaštyl8Adam Weiser9Alexandr Knápek10Vladimír Holcman11Academy of Sciences ČR, Institute of Physics of Materials, Žižkova 22, 616 62 Brno, Czech RepublicDepartment of Physics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Technická 2848/8, 616 00 Brno, Czech RepublicCentral European Institute of Technology BUT, Purkyňova 123, 612 00 Brno, Czech RepublicDepartment of Physics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Technická 2848/8, 616 00 Brno, Czech RepublicDepartment of Physics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Technická 2848/8, 616 00 Brno, Czech RepublicDepartment of Physics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Technická 2848/8, 616 00 Brno, Czech RepublicDepartment of Physics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Technická 2848/8, 616 00 Brno, Czech RepublicDepartment of Inorganic Chemistry and Chemical Ecology, Dagestan State University, St. M. Gadjieva 43-a, 367015 Makhachkala, RussiaCentral European Institute of Technology BUT, Purkyňova 123, 612 00 Brno, Czech RepublicAcademy of Sciences ČR, Institute of Physics of Materials, Žižkova 22, 616 62 Brno, Czech RepublicInstitute of Scientific Instruments of the Czech Academy of Sciences, Královopolská 147, 612 64 Brno, Czech RepublicDepartment of Physics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Technická 2848/8, 616 00 Brno, Czech RepublicThe method of inclusion of various additives into a polymer depends highly on the material in question and the desired effect. In the case of this paper, nitride salts were introduced into polyvinylidene fluoride fibers prepared by electrospinning. The resulting changes in the structural, chemical and electrical properties of the samples were observed and compared using SEM-EDX, DSC, XPS, FTIR, Raman spectroscopy and electrical measurements. The observed results displayed a grouping of parameters by electronegativity and possibly the molecular mass of the additive salts. We virtually demonstrated elimination of the presence of the γ-phase by addition of Mg(NO<sub>3</sub>)<sub>2</sub>, Ca(NO<sub>3</sub>)<sub>2</sub>, and Zn(NO<sub>3</sub>)<sub>2</sub> salts. The trend of electrical properties to follow the electronegativity of the nitrate salt cation is demonstrated. The performed measurements of nitrate salt inclusions into PVDF offer a new insight into effects of previously unstudied structures of PVDF composites, opening new potential possibilities of crystalline phase control of the composite and use in further research and component design.https://www.mdpi.com/2073-4360/13/15/2439PVDFnitrate saltXPSXRDRaman spectroscopyFTIR
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Dinara Sobola Pavel Kaspar Klára Částková Rashid Dallaev Nikola Papež Petr Sedlák Tomáš Trčka Farid Orudzhev Jaroslav Kaštyl Adam Weiser Alexandr Knápek Vladimír Holcman
spellingShingle	Dinara Sobola Pavel Kaspar Klára Částková Rashid Dallaev Nikola Papež Petr Sedlák Tomáš Trčka Farid Orudzhev Jaroslav Kaštyl Adam Weiser Alexandr Knápek Vladimír Holcman PVDF Fibers Modification by Nitrate Salts Doping Polymers PVDF nitrate salt XPS XRD Raman spectroscopy FTIR
author_facet	Dinara Sobola Pavel Kaspar Klára Částková Rashid Dallaev Nikola Papež Petr Sedlák Tomáš Trčka Farid Orudzhev Jaroslav Kaštyl Adam Weiser Alexandr Knápek Vladimír Holcman
author_sort	Dinara Sobola
title	PVDF Fibers Modification by Nitrate Salts Doping
title_short	PVDF Fibers Modification by Nitrate Salts Doping
title_full	PVDF Fibers Modification by Nitrate Salts Doping
title_fullStr	PVDF Fibers Modification by Nitrate Salts Doping
title_full_unstemmed	PVDF Fibers Modification by Nitrate Salts Doping
title_sort	pvdf fibers modification by nitrate salts doping
publisher	MDPI AG
series	Polymers
issn	2073-4360
publishDate	2021-07-01
description	The method of inclusion of various additives into a polymer depends highly on the material in question and the desired effect. In the case of this paper, nitride salts were introduced into polyvinylidene fluoride fibers prepared by electrospinning. The resulting changes in the structural, chemical and electrical properties of the samples were observed and compared using SEM-EDX, DSC, XPS, FTIR, Raman spectroscopy and electrical measurements. The observed results displayed a grouping of parameters by electronegativity and possibly the molecular mass of the additive salts. We virtually demonstrated elimination of the presence of the γ-phase by addition of Mg(NO<sub>3</sub>)<sub>2</sub>, Ca(NO<sub>3</sub>)<sub>2</sub>, and Zn(NO<sub>3</sub>)<sub>2</sub> salts. The trend of electrical properties to follow the electronegativity of the nitrate salt cation is demonstrated. The performed measurements of nitrate salt inclusions into PVDF offer a new insight into effects of previously unstudied structures of PVDF composites, opening new potential possibilities of crystalline phase control of the composite and use in further research and component design.
topic	PVDF nitrate salt XPS XRD Raman spectroscopy FTIR
url	https://www.mdpi.com/2073-4360/13/15/2439
work_keys_str_mv	AT dinarasobola pvdffibersmodificationbynitratesaltsdoping AT pavelkaspar pvdffibersmodificationbynitratesaltsdoping AT klaracastkova pvdffibersmodificationbynitratesaltsdoping AT rashiddallaev pvdffibersmodificationbynitratesaltsdoping AT nikolapapez pvdffibersmodificationbynitratesaltsdoping AT petrsedlak pvdffibersmodificationbynitratesaltsdoping AT tomastrcka pvdffibersmodificationbynitratesaltsdoping AT faridorudzhev pvdffibersmodificationbynitratesaltsdoping AT jaroslavkastyl pvdffibersmodificationbynitratesaltsdoping AT adamweiser pvdffibersmodificationbynitratesaltsdoping AT alexandrknapek pvdffibersmodificationbynitratesaltsdoping AT vladimirholcman pvdffibersmodificationbynitratesaltsdoping
_version_	1721217871865970688

PVDF Fibers Modification by Nitrate Salts Doping

Similar Items