(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one
The molecule of the title compound, C24H19ClN2O2, is bent, with the dihedral angle between the terminal quinoline ring systems being 63.30 (5)°. The quinolinyl residues are connected by an almost planar prop-2-en-1-one bridge (r.m.s. deviation = 0.022 Å), with t...
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| Language: | English |
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International Union of Crystallography
2013-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813019399 |
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doaj-eee4d5bc449348b09e44b9aebb03ec0c2020-11-25T01:57:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698o1274o127410.1107/S1600536813019399(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-oneEdward R. T. TiekinkSeik Weng NgS. SarveswariR. PrasathThe molecule of the title compound, C24H19ClN2O2, is bent, with the dihedral angle between the terminal quinoline ring systems being 63.30 (5)°. The quinolinyl residues are connected by an almost planar prop-2-en-1-one bridge (r.m.s. deviation = 0.022 Å), with the dihedral angles between this plane and the appended quinolinyl residues being 75.86 (7) and 38.54 (7)°. The C atom of the methoxy group is close to coplanar with its attached ring [deviation = 0.116 (2) Å]. In the crystal, a three-dimensional architecture is constructed by methyl–carbonyl C—H...O interactions and π–π interactions between centrosymmetrically related quinolinyl residues [centroid-to-centroid separations 3.5341 (10) and 3.8719 (9) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536813019399 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Edward R. T. Tiekink Seik Weng Ng S. Sarveswari R. Prasath |
| spellingShingle |
Edward R. T. Tiekink Seik Weng Ng S. Sarveswari R. Prasath (2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one Acta Crystallographica Section E |
| author_facet |
Edward R. T. Tiekink Seik Weng Ng S. Sarveswari R. Prasath |
| author_sort |
Edward R. T. Tiekink |
| title |
(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_short |
(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_full |
(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_fullStr |
(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_full_unstemmed |
(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_sort |
(2e)-3-(6-chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2013-08-01 |
| description |
The molecule of the title compound, C24H19ClN2O2, is bent, with the dihedral angle between the terminal quinoline ring systems being 63.30 (5)°. The quinolinyl residues are connected by an almost planar prop-2-en-1-one bridge (r.m.s. deviation = 0.022 Å), with the dihedral angles between this plane and the appended quinolinyl residues being 75.86 (7) and 38.54 (7)°. The C atom of the methoxy group is close to coplanar with its attached ring [deviation = 0.116 (2) Å]. In the crystal, a three-dimensional architecture is constructed by methyl–carbonyl C—H...O interactions and π–π interactions between centrosymmetrically related quinolinyl residues [centroid-to-centroid separations 3.5341 (10) and 3.8719 (9) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813019399 |
| work_keys_str_mv |
AT edwardrttiekink 2e36chloro2methoxyquinolin3yl124dimethylquinolin3ylprop2en1one AT seikwengng 2e36chloro2methoxyquinolin3yl124dimethylquinolin3ylprop2en1one AT ssarveswari 2e36chloro2methoxyquinolin3yl124dimethylquinolin3ylprop2en1one AT rprasath 2e36chloro2methoxyquinolin3yl124dimethylquinolin3ylprop2en1one |
| _version_ |
1724976794147225600 |