Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II)
In the molecule of the title compound, [Ni(C5H4NO3S)2(H2O)4], the NiII cation is located on an inversion center and is coordinated by four water molecules and two pyridine-3-sulfonate anions with an NiN2O4 distorted octahedral geometry. The face-to-face separation of 3.561 (5) &a...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2008-05-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808010076 |
Summary: | In the molecule of the title compound, [Ni(C5H4NO3S)2(H2O)4], the NiII cation is located on an inversion center and is coordinated by four water molecules and two pyridine-3-sulfonate anions with an NiN2O4 distorted octahedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π–π stacking between the pyridine rings. The structure also contains intermolecular O—H...O hydrogen bonding and weak C—H...O hydrogen bonding. |
---|---|
ISSN: | 1600-5368 |