Surface modification of cellulose fibres

Several approaches to the modification of cellulose fibres are described, namely: (i) physical treatments such as corona or plasma treatments under different atmospheres; (ii) grafting with hydrophobic molecules using well-known sizing compounds; (iii) grafting with bi-functional molecules, leaving...

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Bibliographic Details
Main Authors: Mohamed Naceur Belgacem, Alessandro Gandini
Format: Article
Language:English
Published: Associação Brasileira de Polímeros 2005-06-01
Series:Polímeros
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200010
Description
Summary:Several approaches to the modification of cellulose fibres are described, namely: (i) physical treatments such as corona or plasma treatments under different atmospheres; (ii) grafting with hydrophobic molecules using well-known sizing compounds; (iii) grafting with bi-functional molecules, leaving one of the functions available for further exploitation; and (iv) grafting with organometallic compounds. The modified surfaces were characterized by elemental analysis, contact angle measurements, inverse gas chromatography, X-ray photoelectron and infrared spectroscopy, wettability, etc. These different tools provided clear-cut evidence of the occurrence of chemical reactions between the grafting agent used and the hydroxy functions of the cellulose surface, as well as of the existence of covalent bonding in the ensuing composite materials between the matrix and the fibres through the use of doubly reactive coupling agents.
ISSN:0104-1428
1678-5169