Activated Carbons for Syngas Desulfurization: Evaluating Approaches for Enhancing Low-Temperature H₂S Oxidation Rate

• Main Authors: Christian Frilund, Ilkka Hiltunen, Pekka Simell
• Format: Article
• Language: English
• Published: MDPI AG 2021-05-01
• Series: ChemEngineering
• Subjects: syngas desulfurization; activated carbon; hydrogen sulfide; H₂S oxidation; ammonia
• Online Access: https://www.mdpi.com/2305-7084/5/2/23

Its relatively low cost and high surface area makes activated carbon an ideal adsorbent candidate for H₂S removal. However, physical adsorption of H₂S is not very effective; therefore, methods to facilitate reactive H₂S oxidation on carbons are of interest. The performance of H₂S removal of non-impregnated, impregnated, and doped activated carbon in low-temperature syngas was evaluated in fixed-bed breakthrough tests. The importance of oxygen content and relative humidity was established for reactive H₂S removal. Impregnates especially improved the adsorption rate compared to non-impregnated carbons. Non-impregnated carbons could however retain a high capture capacity with sufficient contact time. In a relative performance test, the best performance was achieved by doped activated carbon, 320 mg g⁻¹. Ammonia in syngas was found to significantly improve the adsorption rate of non-impregnated activated carbon. A small quantity of ammonia was consumed by the carbon bed, suggesting that ammonia is a reactant. Finally, to validate ammonia-enhanced desulfurization, bench-scale experiments were performed in biomass-based gasification syngas. The results show that when the ammonia concentration in syngas was in the tens of ppm range, 40–160 ppm H₂S oxidation proceeded rapidly. Ammonia-enhanced oxidation allows utilization of cheaper non-impregnated activated carbons by in situ improvement of the adsorption kinetics. Ammonia enhancement is therefore established as a viable method for achieving high-capacity H₂S removal with unmodified activated carbons.