Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant

Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant

Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)3, from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF3CO)2O/CH2Cl2 system. The colorless, freshly prepared ArI(OCOCF3)2 thus obtained were 98-99% pure (by iodometry).

Bibliographic Details
Main Authors: Lech Skulski, Pawel Kazmierczak
Format: Article
Language:English
Published: MDPI AG 2002-11-01
Series:Molecules
Subjects:
[Bis(trifluoroacetoxy)iodo]arenes from iodoarenes
sodium percarbonate as oxidant
Online Access:http://www.mdpi.com/1420-3049/7/11/810/
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spelling doaj-f0577953718e49bcb16277bdcfa8ca3e2020-11-24T23:54:14ZengMDPI AGMolecules1420-30492002-11-0171181081210.3390/71100810Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the OxidantLech SkulskiPawel KazmierczakEasy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)3, from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF3CO)2O/CH2Cl2 system. The colorless, freshly prepared ArI(OCOCF3)2 thus obtained were 98-99% pure (by iodometry).http://www.mdpi.com/1420-3049/7/11/810/[Bis(trifluoroacetoxy)iodo]arenes from iodoarenessodium percarbonate as oxidant
collection DOAJ
language English
format Article
sources DOAJ
author Lech Skulski
Pawel Kazmierczak
spellingShingle Lech Skulski
Pawel Kazmierczak
Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant
Molecules
[Bis(trifluoroacetoxy)iodo]arenes from iodoarenes
sodium percarbonate as oxidant
author_facet Lech Skulski
Pawel Kazmierczak
author_sort Lech Skulski
title Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant
title_short Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant
title_full Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant
title_fullStr Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant
title_full_unstemmed Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant
title_sort easy preparation of [bis(trifluoroacetoxy)iodo]arenes from iodoarenes, with sodium percarbonate as the oxidant
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2002-11-01
description Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)3, from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF3CO)2O/CH2Cl2 system. The colorless, freshly prepared ArI(OCOCF3)2 thus obtained were 98-99% pure (by iodometry).
topic [Bis(trifluoroacetoxy)iodo]arenes from iodoarenes
sodium percarbonate as oxidant
url http://www.mdpi.com/1420-3049/7/11/810/
work_keys_str_mv AT lechskulski easypreparationofbistrifluoroacetoxyiodoarenesfromiodoareneswithsodiumpercarbonateastheoxidant
AT pawelkazmierczak easypreparationofbistrifluoroacetoxyiodoarenesfromiodoareneswithsodiumpercarbonateastheoxidant
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