Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
Dehydrogenative alkenylation of C-H bonds is an atom-economical approach to prepare more complex olefins. Here, the authors use a combination of decatungstate and a cobaloxime catalyst for the photocatalytic dehydrogenative alkenylation of alkanes and aliphatic aldehydes with aryl alkenes.
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2020-04-01
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Online Access: | https://doi.org/10.1038/s41467-020-15878-6 |
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doaj-f067d196e9b94e1ca56f6ac732f683492021-05-11T08:47:37ZengNature Publishing GroupNature Communications2041-17232020-04-011111810.1038/s41467-020-15878-6Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenesHui Cao0Yulong Kuang1Xiangcheng Shi2Koi Lin Wong3Boon Beng Tan4Jeric Mun Chung Kwan5Xiaogang Liu6Jie Wu7Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Dehydrogenative alkenylation of C-H bonds is an atom-economical approach to prepare more complex olefins. Here, the authors use a combination of decatungstate and a cobaloxime catalyst for the photocatalytic dehydrogenative alkenylation of alkanes and aliphatic aldehydes with aryl alkenes.https://doi.org/10.1038/s41467-020-15878-6 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hui Cao Yulong Kuang Xiangcheng Shi Koi Lin Wong Boon Beng Tan Jeric Mun Chung Kwan Xiaogang Liu Jie Wu |
spellingShingle |
Hui Cao Yulong Kuang Xiangcheng Shi Koi Lin Wong Boon Beng Tan Jeric Mun Chung Kwan Xiaogang Liu Jie Wu Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes Nature Communications |
author_facet |
Hui Cao Yulong Kuang Xiangcheng Shi Koi Lin Wong Boon Beng Tan Jeric Mun Chung Kwan Xiaogang Liu Jie Wu |
author_sort |
Hui Cao |
title |
Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes |
title_short |
Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes |
title_full |
Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes |
title_fullStr |
Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes |
title_full_unstemmed |
Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes |
title_sort |
photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes |
publisher |
Nature Publishing Group |
series |
Nature Communications |
issn |
2041-1723 |
publishDate |
2020-04-01 |
description |
Dehydrogenative alkenylation of C-H bonds is an atom-economical approach to prepare more complex olefins. Here, the authors use a combination of decatungstate and a cobaloxime catalyst for the photocatalytic dehydrogenative alkenylation of alkanes and aliphatic aldehydes with aryl alkenes. |
url |
https://doi.org/10.1038/s41467-020-15878-6 |
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