Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes

Dehydrogenative alkenylation of C-H bonds is an atom-economical approach to prepare more complex olefins. Here, the authors use a combination of decatungstate and a cobaloxime catalyst for the photocatalytic dehydrogenative alkenylation of alkanes and aliphatic aldehydes with aryl alkenes.

Bibliographic Details
Main Authors: Hui Cao, Yulong Kuang, Xiangcheng Shi, Koi Lin Wong, Boon Beng Tan, Jeric Mun Chung Kwan, Xiaogang Liu, Jie Wu
Format: Article
Language:English
Published: Nature Publishing Group 2020-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-15878-6
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spelling doaj-f067d196e9b94e1ca56f6ac732f683492021-05-11T08:47:37ZengNature Publishing GroupNature Communications2041-17232020-04-011111810.1038/s41467-020-15878-6Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenesHui Cao0Yulong Kuang1Xiangcheng Shi2Koi Lin Wong3Boon Beng Tan4Jeric Mun Chung Kwan5Xiaogang Liu6Jie Wu7Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Department of Chemistry, National University of Singapore, 3 Science Drive 3Dehydrogenative alkenylation of C-H bonds is an atom-economical approach to prepare more complex olefins. Here, the authors use a combination of decatungstate and a cobaloxime catalyst for the photocatalytic dehydrogenative alkenylation of alkanes and aliphatic aldehydes with aryl alkenes.https://doi.org/10.1038/s41467-020-15878-6
collection DOAJ
language English
format Article
sources DOAJ
author Hui Cao
Yulong Kuang
Xiangcheng Shi
Koi Lin Wong
Boon Beng Tan
Jeric Mun Chung Kwan
Xiaogang Liu
Jie Wu
spellingShingle Hui Cao
Yulong Kuang
Xiangcheng Shi
Koi Lin Wong
Boon Beng Tan
Jeric Mun Chung Kwan
Xiaogang Liu
Jie Wu
Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
Nature Communications
author_facet Hui Cao
Yulong Kuang
Xiangcheng Shi
Koi Lin Wong
Boon Beng Tan
Jeric Mun Chung Kwan
Xiaogang Liu
Jie Wu
author_sort Hui Cao
title Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
title_short Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
title_full Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
title_fullStr Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
title_full_unstemmed Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
title_sort photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2020-04-01
description Dehydrogenative alkenylation of C-H bonds is an atom-economical approach to prepare more complex olefins. Here, the authors use a combination of decatungstate and a cobaloxime catalyst for the photocatalytic dehydrogenative alkenylation of alkanes and aliphatic aldehydes with aryl alkenes.
url https://doi.org/10.1038/s41467-020-15878-6
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AT xiangchengshi photoinducedsiteselectivealkenylationofalkanesandaldehydeswitharylalkenes
AT koilinwong photoinducedsiteselectivealkenylationofalkanesandaldehydeswitharylalkenes
AT boonbengtan photoinducedsiteselectivealkenylationofalkanesandaldehydeswitharylalkenes
AT jericmunchungkwan photoinducedsiteselectivealkenylationofalkanesandaldehydeswitharylalkenes
AT xiaogangliu photoinducedsiteselectivealkenylationofalkanesandaldehydeswitharylalkenes
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