Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface Methodology

Fe3O4/talc nanocomposite was used for removal of Cu(II), Ni(II), and Pb(II) ions from aqueous solutions. Experiments were designed by response surface methodology (RSM) and a quadratic model was used to predict the variables. The adsorption parameters such as adsorbent dosage, removal time, and init...

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Main Authors: Katayoon Kalantari, Mansor B. Ahmad, Hamid Reza Fard Masoumi, Kamyar Shameli, Mahiran Basri, Roshanak Khandanlou
Format: Article
Language:English
Published: MDPI AG 2014-07-01
Series:International Journal of Molecular Sciences
Subjects:
Online Access:http://www.mdpi.com/1422-0067/15/7/12913
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spelling doaj-f06c0ffe248e49debc687655b9ad91692020-11-24T21:54:01ZengMDPI AGInternational Journal of Molecular Sciences1422-00672014-07-01157129131292710.3390/ijms150712913ijms150712913Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface MethodologyKatayoon Kalantari0Mansor B. Ahmad1Hamid Reza Fard Masoumi2Kamyar Shameli3Mahiran Basri4Roshanak Khandanlou5Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, MalaysiaFe3O4/talc nanocomposite was used for removal of Cu(II), Ni(II), and Pb(II) ions from aqueous solutions. Experiments were designed by response surface methodology (RSM) and a quadratic model was used to predict the variables. The adsorption parameters such as adsorbent dosage, removal time, and initial ion concentration were used as the independent variables and their effects on heavy metal ion removal were investigated. Analysis of variance was incorporated to judge the adequacy of the models. Optimal conditions with initial heavy metal ion concentration of 100, 92 and 270 mg/L, 120 s of removal time and 0.12 g of adsorbent amount resulted in 72.15%, 50.23%, and 91.35% removal efficiency for Cu(II), Ni(II), and Pb(II), respectively. The predictions of the model were in good agreement with experimental results and the Fe3O4/talc nanocomposite was successfully used to remove heavy metals from aqueous solutions.http://www.mdpi.com/1422-0067/15/7/12913heavy metalsFe3O4/talc nanocompositesadsorptionresponse surface methodology (RSM)adsorption kinetics
collection DOAJ
language English
format Article
sources DOAJ
author Katayoon Kalantari
Mansor B. Ahmad
Hamid Reza Fard Masoumi
Kamyar Shameli
Mahiran Basri
Roshanak Khandanlou
spellingShingle Katayoon Kalantari
Mansor B. Ahmad
Hamid Reza Fard Masoumi
Kamyar Shameli
Mahiran Basri
Roshanak Khandanlou
Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface Methodology
International Journal of Molecular Sciences
heavy metals
Fe3O4/talc nanocomposites
adsorption
response surface methodology (RSM)
adsorption kinetics
author_facet Katayoon Kalantari
Mansor B. Ahmad
Hamid Reza Fard Masoumi
Kamyar Shameli
Mahiran Basri
Roshanak Khandanlou
author_sort Katayoon Kalantari
title Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface Methodology
title_short Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface Methodology
title_full Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface Methodology
title_fullStr Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface Methodology
title_full_unstemmed Rapid Adsorption of Heavy Metals by Fe3O4/Talc Nanocomposite and Optimization Study Using Response Surface Methodology
title_sort rapid adsorption of heavy metals by fe3o4/talc nanocomposite and optimization study using response surface methodology
publisher MDPI AG
series International Journal of Molecular Sciences
issn 1422-0067
publishDate 2014-07-01
description Fe3O4/talc nanocomposite was used for removal of Cu(II), Ni(II), and Pb(II) ions from aqueous solutions. Experiments were designed by response surface methodology (RSM) and a quadratic model was used to predict the variables. The adsorption parameters such as adsorbent dosage, removal time, and initial ion concentration were used as the independent variables and their effects on heavy metal ion removal were investigated. Analysis of variance was incorporated to judge the adequacy of the models. Optimal conditions with initial heavy metal ion concentration of 100, 92 and 270 mg/L, 120 s of removal time and 0.12 g of adsorbent amount resulted in 72.15%, 50.23%, and 91.35% removal efficiency for Cu(II), Ni(II), and Pb(II), respectively. The predictions of the model were in good agreement with experimental results and the Fe3O4/talc nanocomposite was successfully used to remove heavy metals from aqueous solutions.
topic heavy metals
Fe3O4/talc nanocomposites
adsorption
response surface methodology (RSM)
adsorption kinetics
url http://www.mdpi.com/1422-0067/15/7/12913
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