Design and characterization of ceramic hollow fiber membrane derived from waste ash using phase inversion-based extrusion/sintering technique for water filtration

• Main Authors: Zhong Sheng Tai, Mohd Hafiz Dzarfan Othman, Azeman Mustafa, Mohd Irfan Hatim Mohamed Dzahir, Siti Khadijah Hubadillah, Khong Nee Koo, Mohd Ariff Azali, Nur Hashimah Alias, Boon Seng Ooi, Tonni Agustiono Kurniawan, Ahmad Fauzi Ismail
• Format: Article
• Language: English
• Published: Taylor & Francis Group 2021-01-01
• Series: Journal of Asian Ceramic Societies
• Subjects: palm oil fuel ash; ceramic hollow fiber membrane; membrane morphology; phase inversion; sintering
• Online Access: http://dx.doi.org/10.1080/21870764.2020.1868080

Low-cost green ceramic hollow fiber membranes (CHFM) were successfully designed and fabricated from the industrial waste ash, palm oil fuel ash (POFA) via phase inversion-based extrusion/sintering techniques for water filtration application. The extrusion process parameters such as suspension viscosity, air gap distance, and bore fluid flow rate were systematically explored to produce the membrane with desired morphology. A high suspension viscosity would result in a small macro-voids structure. Moreover, a high air gap distance would induce fiber with long macro-voids structure, while a low bore fluid flow rate would lead to the formation of distorted lumen structure. The effect of sintering temperature toward CHFM was also studied and characterized. An increase in the sintering temperature improved the membrane bending strength, but also afflicted the flux performance due to lower porosity and higher tortuosity. The developed membranes achieved excellent bending strengths of >75 MPa at lower sintering temperatures than the alternative ceramic counterparts, due to the formation of the eutectic liquid during sintering. The relatively low sintering temperature of POFA-derived CHFMs could reduce the energy consumption and sintering duration, which could be more economically attractive than their ceramic counterparts, thus benefiting industrial users.