Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)

The synthesis and properties of a series of bis-tetrathiafulvalenes (bis-TTFs) containing nitrophenyl, aminophenyl or dimethylaminophenyl is reported. The synthesis was carried out by using routes involving Wittig-type, cross-coupling, reduction and alkylation reactions. The electron donor ability o...

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Main Authors:	Didier Villemin, Zine Regainia, Abdelkrim Gouasmia, Amel Bendjeddou, Tahar Abbaz
Format:	Article
Language:	English
Published:	MDPI AG 2012-06-01
Series:	International Journal of Molecular Sciences
Subjects:	tetrathiafulvalenes redox potentials organic materials conductivity
Online Access:	http://www.mdpi.com/1422-0067/13/7/7872

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spelling	doaj-f1d8385354d741c5b124cd4cd53b2c922020-11-24T20:43:55ZengMDPI AGInternational Journal of Molecular Sciences1422-00672012-06-011377872788510.3390/ijms13077872Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)Didier VilleminZine RegainiaAbdelkrim GouasmiaAmel BendjeddouTahar AbbazThe synthesis and properties of a series of bis-tetrathiafulvalenes (bis-TTFs) containing nitrophenyl, aminophenyl or dimethylaminophenyl is reported. The synthesis was carried out by using routes involving Wittig-type, cross-coupling, reduction and alkylation reactions. The electron donor ability of these new compounds has been measured by cyclic voltammetry (CV). Charge transfer complexes with tetracyanoquinodimethane (TCNQ) were prepared by chemical redox reactions. The complexes have been proven to give conducting materials.http://www.mdpi.com/1422-0067/13/7/7872tetrathiafulvalenesredox potentialsorganic materialsconductivity
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Didier Villemin Zine Regainia Abdelkrim Gouasmia Amel Bendjeddou Tahar Abbaz
spellingShingle	Didier Villemin Zine Regainia Abdelkrim Gouasmia Amel Bendjeddou Tahar Abbaz Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ) International Journal of Molecular Sciences tetrathiafulvalenes redox potentials organic materials conductivity
author_facet	Didier Villemin Zine Regainia Abdelkrim Gouasmia Amel Bendjeddou Tahar Abbaz
author_sort	Didier Villemin
title	Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)
title_short	Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)
title_full	Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)
title_fullStr	Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)
title_full_unstemmed	Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)
title_sort	synthesis and electrochemical proprieties of novel unsymmetrical bis-tetrathiafulvalenes and electrical conductivity of their charge transfer complexes with tetracyanoquinodimethane (tcnq)
publisher	MDPI AG
series	International Journal of Molecular Sciences
issn	1422-0067
publishDate	2012-06-01
description	The synthesis and properties of a series of bis-tetrathiafulvalenes (bis-TTFs) containing nitrophenyl, aminophenyl or dimethylaminophenyl is reported. The synthesis was carried out by using routes involving Wittig-type, cross-coupling, reduction and alkylation reactions. The electron donor ability of these new compounds has been measured by cyclic voltammetry (CV). Charge transfer complexes with tetracyanoquinodimethane (TCNQ) were prepared by chemical redox reactions. The complexes have been proven to give conducting materials.
topic	tetrathiafulvalenes redox potentials organic materials conductivity
url	http://www.mdpi.com/1422-0067/13/7/7872
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Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ)

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