Innovative Organocatalysis — Perspective Trend in Reactions of Liquid Phase Oxidation Reactions with Molecular Oxygen
Innovations in the organocatalytic aerobic oxidation and significant advances achieved in this field in in POCC of NASof Ukraine are presented. An important innovation of the oxidation of hydrocarbons and 5-hydroxymethylfurfural under mild conditions with molecular oxygen was achieved by using the o...
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| Format: | Article |
| Language: | Ukrainian |
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Publishing House "Akademperiodyka"
2015-11-01
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| Series: | Nauka ta Innovacii |
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| Online Access: | ftp://nas.gov.ua/akademperiodyka/Downloads/Archive%20SI%20Journal/SI_ukr/2015/N6/Opeida.pdf |
| Summary: | Innovations in the organocatalytic aerobic oxidation and significant advances achieved in this field in in POCC of NASof Ukraine are presented. An important innovation of the oxidation of hydrocarbons and 5-hydroxymethylfurfural under mild conditions with molecular oxygen was achieved by using the organic compound — N-hydroxyphthalimide as a key catalyst. In the case of oxidation of coal and substrates, the molecules of which are capable of keto-enol tautomerism, it is the innovative to use dimethyl sulfoxide as a solvent, which provides basic catalysis. |
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| ISSN: | 1815-2066 2413-497X |