Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane

Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane

Perovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPSmethods. Their catalytic behavior in the total oxidation of hexane was examined....

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Main Authors: Zhong H., Zeng R.
Format: Article
Language:English
Published: Serbian Chemical Society 2006-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
perovskite-type lasrmo4
hexane oxidation
catalytic property
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610049Z.pdf
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spelling doaj-f36bf7d8237346dc9d75063e2e7ebd602020-12-24T14:31:03ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74212006-01-0171101049105910.2298/JSC0610049Z0352-51390610049ZStructure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexaneZhong H.0Zeng R.1Provincial key laboratory of coordination chemistry, Jinggangshan University, Jian, College of chemistry and chemical engineering, Jinggangshan University, JianProvincial key laboratory of coordination chemistry, Jinggangshan University, Jian, College of chemistry and chemical engineering, Jinggangshan University, JianPerovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPSmethods. Their catalytic behavior in the total oxidation of hexane was examined. The following activity order was found LaSrCoO4 > LaSrNiO4 > LaSrCuO4 > LaSrFeO4 > LaSrMnO4. This is explained in terms of oxygen vacancies and mobile lattice oxygen, particle size and BET surface area. .http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610049Z.pdfperovskite-type lasrmo4hexane oxidationcatalytic property
collection DOAJ
language English
format Article
sources DOAJ
author Zhong H.
Zeng R.
spellingShingle Zhong H.
Zeng R.
Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
Journal of the Serbian Chemical Society
perovskite-type lasrmo4
hexane oxidation
catalytic property
author_facet Zhong H.
Zeng R.
author_sort Zhong H.
title Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
title_short Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
title_full Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
title_fullStr Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
title_full_unstemmed Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
title_sort structure of lasrmo4(m = mn, fe, co, ni, cu) and their catalytic properties in the total oxidation of hexane
publisher Serbian Chemical Society
series Journal of the Serbian Chemical Society
issn 0352-5139
1820-7421
publishDate 2006-01-01
description Perovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPSmethods. Their catalytic behavior in the total oxidation of hexane was examined. The following activity order was found LaSrCoO4 > LaSrNiO4 > LaSrCuO4 > LaSrFeO4 > LaSrMnO4. This is explained in terms of oxygen vacancies and mobile lattice oxygen, particle size and BET surface area. .
topic perovskite-type lasrmo4
hexane oxidation
catalytic property
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610049Z.pdf
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