Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA)
Barite (BaSO4) speleothems have been reported from caves around the globe and interpreted to have chiefly formed in phreatic, hypogene, hydrothermal settings. Here we report two contrasting types of barite speleothems (bluish tabular crystals in a shallow pool and actively dripping greenish stalacti...
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doaj-f3d92605129c4b36ba860d282ef6d07f2021-05-02T21:39:54ZengUniversity of South Florida LibrariesInternational Journal of Speleology0392-66721827-806X2020-01-01491112610.5038/1827-806X.49.1.2280Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA)Max Wisshak0https://orcid.org/0000-0001-7531-3317Hazel A. Barton1Katey E. Bender2Harvey R. DuChene3Senckenberg am Meer, Marine Research DepartmentUniversity of AkronUniversity of AkronPO Box 362, Lake City, CO 81235, USABarite (BaSO4) speleothems have been reported from caves around the globe and interpreted to have chiefly formed in phreatic, hypogene, hydrothermal settings. Here we report two contrasting types of barite speleothems (bluish tabular crystals in a shallow pool and actively dripping greenish stalactites), which today form at lower temperatures in the non-hydrothermal and vadose environment of Lechuguilla Cave, New Mexico, USA. Scanning electron microscopy analysis, along with energy- and wavelength-dispersive X-ray spectroscopy (EDS, WDS), as well as X-ray diffraction (XRD), characterize the habit and chemical composition as barite. Fractionation of the minor element calcium is related to growth along different crystal faces whereas variations in strontium concentration are mirrored in blue color zoning of the pool crystals. Two possible modes of non-hydrothermal barite precipitation are discussed: (1) intense evaporation driven by thermal atmospheric convection cells or (2) mixing of barium-rich, sulfate-poor water with water rich in sulfate. Both processes, in isolation or in combination, lead to supersaturation and could explain formation of the investigated barite speleothems. Observations of three types of microbes on the pool barite crystals showing evidence of incrustation raises the question whether there is a potential involvement of microbial activity in the temperate barite precipitation in Lechuguilla Cave.https://scholarcommons.usf.edu/ijs/vol49/iss1/2/baritespeleothemprecipitationmicrobesincrustation |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Max Wisshak Hazel A. Barton Katey E. Bender Harvey R. DuChene |
spellingShingle |
Max Wisshak Hazel A. Barton Katey E. Bender Harvey R. DuChene Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA) International Journal of Speleology barite speleothem precipitation microbes incrustation |
author_facet |
Max Wisshak Hazel A. Barton Katey E. Bender Harvey R. DuChene |
author_sort |
Max Wisshak |
title |
Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA) |
title_short |
Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA) |
title_full |
Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA) |
title_fullStr |
Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA) |
title_full_unstemmed |
Active growth of non-hydrothermal subaqueous and subaerial barite (BaSO4) speleothems in Lechuguilla Cave (New Mexico, USA) |
title_sort |
active growth of non-hydrothermal subaqueous and subaerial barite (baso4) speleothems in lechuguilla cave (new mexico, usa) |
publisher |
University of South Florida Libraries |
series |
International Journal of Speleology |
issn |
0392-6672 1827-806X |
publishDate |
2020-01-01 |
description |
Barite (BaSO4) speleothems have been reported from caves around the globe and interpreted to have chiefly formed in phreatic, hypogene, hydrothermal settings. Here we report two contrasting types of barite speleothems (bluish tabular crystals in a shallow pool and actively dripping greenish stalactites), which today form at lower temperatures in the non-hydrothermal and vadose environment of Lechuguilla Cave, New Mexico, USA. Scanning electron microscopy analysis, along with energy- and wavelength-dispersive X-ray spectroscopy (EDS, WDS), as well as X-ray diffraction (XRD), characterize the habit and chemical composition as barite. Fractionation of the minor element calcium is related to growth along different crystal faces whereas variations in strontium concentration are mirrored in blue color zoning of the pool crystals. Two possible modes of non-hydrothermal barite precipitation are discussed: (1) intense evaporation driven by thermal atmospheric convection cells or (2) mixing of barium-rich, sulfate-poor water with water rich in sulfate. Both processes, in isolation or in combination, lead to supersaturation and could explain formation of the investigated barite speleothems. Observations of three types of microbes on the pool barite crystals showing evidence of incrustation raises the question whether there is a potential involvement of microbial activity in the temperate barite precipitation in Lechuguilla Cave. |
topic |
barite speleothem precipitation microbes incrustation |
url |
https://scholarcommons.usf.edu/ijs/vol49/iss1/2/ |
work_keys_str_mv |
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