Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))

Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))

The title dinuclear complex, [Cu2Br2(C12H14N4S2)2], is located about an inversion center. The CuI ion is coordinated in a distorted tetrahedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine ligand. In th...

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Main Authors: Yupa Wattanakanjana, Ruthairat Nimthong, Chaveng Pakawatchai
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812016315
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spelling doaj-f407647ed0204176b769aa8c8d54394f2020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m645m64510.1107/S1600536812016315Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))Yupa WattanakanjanaRuthairat NimthongChaveng PakawatchaiThe title dinuclear complex, [Cu2Br2(C12H14N4S2)2], is located about an inversion center. The CuI ion is coordinated in a distorted tetrahedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine ligand. In the crystal, π–π stacking interactions are observed with a centroid–centroid distance of 3.590 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812016315
collection DOAJ
language English
format Article
sources DOAJ
author Yupa Wattanakanjana
Ruthairat Nimthong
Chaveng Pakawatchai
spellingShingle Yupa Wattanakanjana
Ruthairat Nimthong
Chaveng Pakawatchai
Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))
Acta Crystallographica Section E
author_facet Yupa Wattanakanjana
Ruthairat Nimthong
Chaveng Pakawatchai
author_sort Yupa Wattanakanjana
title Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))
title_short Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))
title_full Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))
title_fullStr Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))
title_full_unstemmed Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2N1,S2}copper(I))
title_sort di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2n1,s2}copper(i))
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description The title dinuclear complex, [Cu2Br2(C12H14N4S2)2], is located about an inversion center. The CuI ion is coordinated in a distorted tetrahedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine ligand. In the crystal, π–π stacking interactions are observed with a centroid–centroid distance of 3.590 (2) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812016315
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AT ruthairatnimthong diamp956bromidobis246dimethylpyrimidin2yldisulfanyl46dimethylpyrimidineamp9542n1s2copperi
AT chavengpakawatchai diamp956bromidobis246dimethylpyrimidin2yldisulfanyl46dimethylpyrimidineamp9542n1s2copperi
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