Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)
In the title compound, [Ni(C15H13FNO2)2], the NiII atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the NiII atom are trans to each other, as the NiII atom l...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-08-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811025189 |
id |
doaj-f48daf32b8d141afab16aa2c04d745e2 |
---|---|
record_format |
Article |
spelling |
doaj-f48daf32b8d141afab16aa2c04d745e22020-11-25T00:53:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1010m101110.1107/S1600536811025189Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)Hadariah BahronAmalina Mohd TajuddinWan Nazihah Wan IbrahimMadhukar HemamaliniHoong-Kun FunIn the title compound, [Ni(C15H13FNO2)2], the NiII atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the NiII atom are trans to each other, as the NiII atom lies on an inversion centre. In the fluorophenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via intermolecular C—H...F hydrogen bonds, forming chains along [001].http://scripts.iucr.org/cgi-bin/paper?S1600536811025189 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hadariah Bahron Amalina Mohd Tajuddin Wan Nazihah Wan Ibrahim Madhukar Hemamalini Hoong-Kun Fun |
spellingShingle |
Hadariah Bahron Amalina Mohd Tajuddin Wan Nazihah Wan Ibrahim Madhukar Hemamalini Hoong-Kun Fun Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II) Acta Crystallographica Section E |
author_facet |
Hadariah Bahron Amalina Mohd Tajuddin Wan Nazihah Wan Ibrahim Madhukar Hemamalini Hoong-Kun Fun |
author_sort |
Hadariah Bahron |
title |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II) |
title_short |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II) |
title_full |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II) |
title_fullStr |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II) |
title_full_unstemmed |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II) |
title_sort |
bis{2-[(e)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2n,o1}nickel(ii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-08-01 |
description |
In the title compound, [Ni(C15H13FNO2)2], the NiII atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the NiII atom are trans to each other, as the NiII atom lies on an inversion centre. In the fluorophenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via intermolecular C—H...F hydrogen bonds, forming chains along [001]. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811025189 |
work_keys_str_mv |
AT hadariahbahron bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii AT amalinamohdtajuddin bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii AT wannazihahwanibrahim bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii AT madhukarhemamalini bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii AT hoongkunfun bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii |
_version_ |
1725237160565538816 |