Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)

Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)

In the title compound, [Ni(C15H13FNO2)2], the NiII atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the NiII atom are trans to each other, as the NiII atom l...

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Main Authors: Hadariah Bahron, Amalina Mohd Tajuddin, Wan Nazihah Wan Ibrahim, Madhukar Hemamalini, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811025189
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spelling doaj-f48daf32b8d141afab16aa2c04d745e22020-11-25T00:53:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1010m101110.1107/S1600536811025189Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)Hadariah BahronAmalina Mohd TajuddinWan Nazihah Wan IbrahimMadhukar HemamaliniHoong-Kun FunIn the title compound, [Ni(C15H13FNO2)2], the NiII atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the NiII atom are trans to each other, as the NiII atom lies on an inversion centre. In the fluorophenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via intermolecular C—H...F hydrogen bonds, forming chains along [001].http://scripts.iucr.org/cgi-bin/paper?S1600536811025189
collection DOAJ
language English
format Article
sources DOAJ
author Hadariah Bahron
Amalina Mohd Tajuddin
Wan Nazihah Wan Ibrahim
Madhukar Hemamalini
Hoong-Kun Fun
spellingShingle Hadariah Bahron
Amalina Mohd Tajuddin
Wan Nazihah Wan Ibrahim
Madhukar Hemamalini
Hoong-Kun Fun
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)
Acta Crystallographica Section E
author_facet Hadariah Bahron
Amalina Mohd Tajuddin
Wan Nazihah Wan Ibrahim
Madhukar Hemamalini
Hoong-Kun Fun
author_sort Hadariah Bahron
title Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)
title_short Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)
title_full Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)
title_fullStr Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)
title_full_unstemmed Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2N,O1}nickel(II)
title_sort bis{2-[(e)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ2n,o1}nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-08-01
description In the title compound, [Ni(C15H13FNO2)2], the NiII atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the NiII atom are trans to each other, as the NiII atom lies on an inversion centre. In the fluorophenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via intermolecular C—H...F hydrogen bonds, forming chains along [001].
url http://scripts.iucr.org/cgi-bin/paper?S1600536811025189
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AT amalinamohdtajuddin bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii
AT wannazihahwanibrahim bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii
AT madhukarhemamalini bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii
AT hoongkunfun bis2e4fluorobenzyliminomethyl6methoxyphenolatoamp9542no1nickelii
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