catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]

catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]

The title compound, {[Zn(C3H3N2)(C3H4N2)2]NO3}n, is a one-dimensional coordination polymer along [01-1] with the ZnII atom coordinating to four imidazole/imidazolide rings. The ZnII atom has a regular tetrahedral geometry with the planes of the two monodentate imidazole rings inclined to one another...

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Bibliographic Details
Main Authors: Elumalai Govindhan, A. S. Ganeshraja, B. Bhavana, Krishnamoorthy Anbalagan, Arunachalam SubbiahPandi
Format: Article
Language:English
Published: International Union of Crystallography 2014-08-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814015232
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spelling doaj-f4d0dc199bc64127b1f7f57c3cc570402020-11-24T21:49:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-08-01708m298m29910.1107/S1600536814015232su2723catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]Elumalai Govindhan0A. S. Ganeshraja1B. Bhavana2Krishnamoorthy Anbalagan3Arunachalam SubbiahPandi4Department of Physics, Presidency College, Chennai 600 005, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Physics, Presidency College, Chennai 600 005, IndiaThe title compound, {[Zn(C3H3N2)(C3H4N2)2]NO3}n, is a one-dimensional coordination polymer along [01-1] with the ZnII atom coordinating to four imidazole/imidazolide rings. The ZnII atom has a regular tetrahedral geometry with the planes of the two monodentate imidazole rings inclined to one another by 87.94 (17)°, while the planes of the bridging imidazolide rings are inclined to one another by 39.06 (17)°. In the crystal, the chains are linked via bifurcated N—H...(O,O) hydrogen bonds, forming sheets parallel to (001). These two-dimensional networks are linked via C—H...O hydrogen bonds and a C—H...π interaction, forming a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S1600536814015232crystal structure
collection DOAJ
language English
format Article
sources DOAJ
author Elumalai Govindhan
A. S. Ganeshraja
B. Bhavana
Krishnamoorthy Anbalagan
Arunachalam SubbiahPandi
spellingShingle Elumalai Govindhan
A. S. Ganeshraja
B. Bhavana
Krishnamoorthy Anbalagan
Arunachalam SubbiahPandi
catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]
Acta Crystallographica Section E
crystal structure
author_facet Elumalai Govindhan
A. S. Ganeshraja
B. Bhavana
Krishnamoorthy Anbalagan
Arunachalam SubbiahPandi
author_sort Elumalai Govindhan
title catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]
title_short catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]
title_full catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]
title_fullStr catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]
title_full_unstemmed catena-Poly[[[bis(1H-imidazole-κN3)zinc(II)]-μ2-imidazol-1-ido-κ2N:N′] nitrate]
title_sort catena-poly[[[bis(1h-imidazole-κn3)zinc(ii)]-μ2-imidazol-1-ido-κ2n:n′] nitrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-08-01
description The title compound, {[Zn(C3H3N2)(C3H4N2)2]NO3}n, is a one-dimensional coordination polymer along [01-1] with the ZnII atom coordinating to four imidazole/imidazolide rings. The ZnII atom has a regular tetrahedral geometry with the planes of the two monodentate imidazole rings inclined to one another by 87.94 (17)°, while the planes of the bridging imidazolide rings are inclined to one another by 39.06 (17)°. In the crystal, the chains are linked via bifurcated N—H...(O,O) hydrogen bonds, forming sheets parallel to (001). These two-dimensional networks are linked via C—H...O hydrogen bonds and a C—H...π interaction, forming a three-dimensional structure.
topic crystal structure
url http://scripts.iucr.org/cgi-bin/paper?S1600536814015232
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AT asganeshraja catenapolybis1himidazolekn3zinciim2imidazol1idok2nnnitrate
AT bbhavana catenapolybis1himidazolekn3zinciim2imidazol1idok2nnnitrate
AT krishnamoorthyanbalagan catenapolybis1himidazolekn3zinciim2imidazol1idok2nnnitrate
AT arunachalamsubbiahpandi catenapolybis1himidazolekn3zinciim2imidazol1idok2nnnitrate
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