LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIO
This paper describes a route for recovering cobalt and lithium from spent Li-ion batteries via acidic leaching. Sulfuric, hydrochloric, hydrofluoric and formic acids were used as leachants. Hydrogen peroxide was added as reductant, except for formic acid since it is itself a reductant. Experiments w...
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doaj-f632f19274a444c4a8a373463fd8c32f2020-11-24T23:25:32ZengSociedade Brasileira de QuímicaQuímica Nova1678-706441558158610.21577/0100-4042.20170207S0100-40422018000500581LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIORafael Gundim SilvaJúlio Carlos AfonsoClaudio Fernando MahlerThis paper describes a route for recovering cobalt and lithium from spent Li-ion batteries via acidic leaching. Sulfuric, hydrochloric, hydrofluoric and formic acids were used as leachants. Hydrogen peroxide was added as reductant, except for formic acid since it is itself a reductant. Experiments were run at 25-40 ºC for 1-3 h. Under the best optimal conditions, the leaching efficiency order was HCl ≈ HF > H2SO4 > HCOOH. Over 90 wt.% of cobalt and lithium were leached by the inorganic acids. The insoluble matter corresponds mainly to the carbon from the cathode. Co(II) was extracted with D2EHPA 16 vol.% diluted in n-hexane at pH ~5 (A/O ratio 1/1 vol/vol, one stage, 25 ºC). Co(II) striping was possible using a dilute leachant (1-2 mol L-1 HCl or H2SO4, 4-5 mol L-1 HF or HCOOH). Lithium was isolated from the raffinate by precipitation as carbonate or phosphate.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000500581&lng=en&tlng=enlithium-ion batterymetals recoverysolvent extractioncobaltlithium |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Rafael Gundim Silva Júlio Carlos Afonso Claudio Fernando Mahler |
spellingShingle |
Rafael Gundim Silva Júlio Carlos Afonso Claudio Fernando Mahler LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIO Química Nova lithium-ion battery metals recovery solvent extraction cobalt lithium |
author_facet |
Rafael Gundim Silva Júlio Carlos Afonso Claudio Fernando Mahler |
author_sort |
Rafael Gundim Silva |
title |
LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIO |
title_short |
LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIO |
title_full |
LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIO |
title_fullStr |
LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIO |
title_full_unstemmed |
LIXIVIAÇÃO ÁCIDA DE BATERIAS ÍON-LÍTIO |
title_sort |
lixiviação ácida de baterias íon-lítio |
publisher |
Sociedade Brasileira de Química |
series |
Química Nova |
issn |
1678-7064 |
description |
This paper describes a route for recovering cobalt and lithium from spent Li-ion batteries via acidic leaching. Sulfuric, hydrochloric, hydrofluoric and formic acids were used as leachants. Hydrogen peroxide was added as reductant, except for formic acid since it is itself a reductant. Experiments were run at 25-40 ºC for 1-3 h. Under the best optimal conditions, the leaching efficiency order was HCl ≈ HF > H2SO4 > HCOOH. Over 90 wt.% of cobalt and lithium were leached by the inorganic acids. The insoluble matter corresponds mainly to the carbon from the cathode. Co(II) was extracted with D2EHPA 16 vol.% diluted in n-hexane at pH ~5 (A/O ratio 1/1 vol/vol, one stage, 25 ºC). Co(II) striping was possible using a dilute leachant (1-2 mol L-1 HCl or H2SO4, 4-5 mol L-1 HF or HCOOH). Lithium was isolated from the raffinate by precipitation as carbonate or phosphate. |
topic |
lithium-ion battery metals recovery solvent extraction cobalt lithium |
url |
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000500581&lng=en&tlng=en |
work_keys_str_mv |
AT rafaelgundimsilva lixiviacaoacidadebateriasionlitio AT juliocarlosafonso lixiviacaoacidadebateriasionlitio AT claudiofernandomahler lixiviacaoacidadebateriasionlitio |
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1725557085349871616 |