cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)

The title compound, cis-[Re(C12H24O4P)Cl2O(C18H15P)], was prepared from the analogous trans isomer [Głowiak et al. (2000). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The ReV atom adopts a distorted octahedral coordination geometry. Besi...

Full description

Bibliographic Details
Main Authors: Andrzej Gniewek, Miłosz Siczek, Anna Skarżyńska
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812015565
Description
Summary:The title compound, cis-[Re(C12H24O4P)Cl2O(C18H15P)], was prepared from the analogous trans isomer [Głowiak et al. (2000). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The ReV atom adopts a distorted octahedral coordination geometry. Besides being coordinated by the oxide and the butanolate O atoms, the ReV atom is coordinated by a pair of chloride ligands and two P atoms in cis positions with respect to each other. In the crystal, adjacent molecules are linked by weak C—H...Cl interactions, forming a three-dimensional network.
ISSN:1600-5368