cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)
The title compound, cis-[Re(C12H24O4P)Cl2O(C18H15P)], was prepared from the analogous trans isomer [Głowiak et al. (2000). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The ReV atom adopts a distorted octahedral coordination geometry. Besi...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2012-05-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812015565 |
Summary: | The title compound, cis-[Re(C12H24O4P)Cl2O(C18H15P)], was prepared from the analogous trans isomer [Głowiak et al. (2000). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The ReV atom adopts a distorted octahedral coordination geometry. Besides being coordinated by the oxide and the butanolate O atoms, the ReV atom is coordinated by a pair of chloride ligands and two P atoms in cis positions with respect to each other. In the crystal, adjacent molecules are linked by weak C—H...Cl interactions, forming a three-dimensional network. |
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ISSN: | 1600-5368 |