catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]

catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]

The CuII atoms in the title coordination polymer, {[Cu(C13H11N4O)(C2N3)]·H2O}n, are N,N′,O-chelated by the deprotonated Schiff base ligands, and adjacent metal atoms are bridged by the dicyanamide ions, generating a polymeric chain that propagates along the b axis. The two...

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Main Authors: Roji J. Kunnath, M.R. Prathapachandra Kurup, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2012-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812035283
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spelling doaj-f684aa56e5db445b91009fa0ab6dbcfb2020-11-24T21:21:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1176m117610.1107/S1600536812035283catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]Roji J. KunnathM.R. Prathapachandra KurupSeik Weng NgThe CuII atoms in the title coordination polymer, {[Cu(C13H11N4O)(C2N3)]·H2O}n, are N,N′,O-chelated by the deprotonated Schiff base ligands, and adjacent metal atoms are bridged by the dicyanamide ions, generating a polymeric chain that propagates along the b axis. The two independent metal atoms show a square-pyramidal N4O coordination. The two independent water molecules are disordered over two positions; each water molecule is a hydrogen-bond donor to a carbonyl O atom. Weak N—H...N hydrogen bonding is also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812035283
collection DOAJ
language English
format Article
sources DOAJ
author Roji J. Kunnath
M.R. Prathapachandra Kurup
Seik Weng Ng
spellingShingle Roji J. Kunnath
M.R. Prathapachandra Kurup
Seik Weng Ng
catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]
Acta Crystallographica Section E
author_facet Roji J. Kunnath
M.R. Prathapachandra Kurup
Seik Weng Ng
author_sort Roji J. Kunnath
title catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]
title_short catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]
title_full catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]
title_fullStr catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]
title_full_unstemmed catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ2N1,O}copper(II)]-μ-dicyanamido-κ2N1:N5] monohydrate]
title_sort catena-poly[[[{1-[(e)-phenyl(pyridin-2-yl-κn)methylidene]semicarbazidato-κ2n1,o}copper(ii)]-μ-dicyanamido-κ2n1:n5] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-09-01
description The CuII atoms in the title coordination polymer, {[Cu(C13H11N4O)(C2N3)]·H2O}n, are N,N′,O-chelated by the deprotonated Schiff base ligands, and adjacent metal atoms are bridged by the dicyanamide ions, generating a polymeric chain that propagates along the b axis. The two independent metal atoms show a square-pyramidal N4O coordination. The two independent water molecules are disordered over two positions; each water molecule is a hydrogen-bond donor to a carbonyl O atom. Weak N—H...N hydrogen bonding is also observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812035283
work_keys_str_mv AT rojijkunnath catenapoly1ephenylpyridin2ylamp954nmethylidenesemicarbazidatoamp9542n1ocopperiiamp956dicyanamidoamp9542n1n5monohydrate
AT mrprathapachandrakurup catenapoly1ephenylpyridin2ylamp954nmethylidenesemicarbazidatoamp9542n1ocopperiiamp956dicyanamidoamp9542n1n5monohydrate
AT seikwengng catenapoly1ephenylpyridin2ylamp954nmethylidenesemicarbazidatoamp9542n1ocopperiiamp956dicyanamidoamp9542n1n5monohydrate
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