Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels

Confinement of polymers in nano-spaces can induce unique molecular dynamics and properties. Here the authors show high mass fractionation by the confinement of single polymer chains of poly(ethylene oxide) in the one-dimensional channels of crystalline pillar[5]arene.

Bibliographic Details
Main Authors: Tomoki Ogoshi, Ryuta Sueto, Masafumi Yagyu, Ryosuke Kojima, Takahiro Kakuta, Tada-aki Yamagishi, Kazuki Doitomi, Anil Kumar Tummanapelli, Hajime Hirao, Yoko Sakata, Shigehisa Akine, Motohiro Mizuno
Format: Article
Language:English
Published: Nature Publishing Group 2019-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-08372-1
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spelling doaj-f6d95822ca6d481cae6309838213d83f2021-05-11T12:17:39ZengNature Publishing GroupNature Communications2041-17232019-01-011011810.1038/s41467-019-08372-1Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channelsTomoki Ogoshi0Ryuta Sueto1Masafumi Yagyu2Ryosuke Kojima3Takahiro Kakuta4Tada-aki Yamagishi5Kazuki Doitomi6Anil Kumar Tummanapelli7Hajime Hirao8Yoko Sakata9Shigehisa Akine10Motohiro Mizuno11Graduate School of Natural Science and Technology, Kanazawa UniversityGraduate School of Natural Science and Technology, Kanazawa UniversityGraduate School of Natural Science and Technology, Kanazawa UniversityGraduate School of Natural Science and Technology, Kanazawa UniversityGraduate School of Natural Science and Technology, Kanazawa UniversityGraduate School of Natural Science and Technology, Kanazawa UniversityDepartment of Chemistry, City University of Hong Kong, Tat Chee AvenueDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityJapan Science and Technology Agency (JST), Precursory Research for Embryonic Science and Technology (PRESTO), 4-1-8 HonchoGraduate School of Natural Science and Technology, Kanazawa UniversityGraduate School of Natural Science and Technology, Kanazawa UniversityGraduate School of Natural Science and Technology, Kanazawa UniversityConfinement of polymers in nano-spaces can induce unique molecular dynamics and properties. Here the authors show high mass fractionation by the confinement of single polymer chains of poly(ethylene oxide) in the one-dimensional channels of crystalline pillar[5]arene.https://doi.org/10.1038/s41467-019-08372-1
collection DOAJ
language English
format Article
sources DOAJ
author Tomoki Ogoshi
Ryuta Sueto
Masafumi Yagyu
Ryosuke Kojima
Takahiro Kakuta
Tada-aki Yamagishi
Kazuki Doitomi
Anil Kumar Tummanapelli
Hajime Hirao
Yoko Sakata
Shigehisa Akine
Motohiro Mizuno
spellingShingle Tomoki Ogoshi
Ryuta Sueto
Masafumi Yagyu
Ryosuke Kojima
Takahiro Kakuta
Tada-aki Yamagishi
Kazuki Doitomi
Anil Kumar Tummanapelli
Hajime Hirao
Yoko Sakata
Shigehisa Akine
Motohiro Mizuno
Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels
Nature Communications
author_facet Tomoki Ogoshi
Ryuta Sueto
Masafumi Yagyu
Ryosuke Kojima
Takahiro Kakuta
Tada-aki Yamagishi
Kazuki Doitomi
Anil Kumar Tummanapelli
Hajime Hirao
Yoko Sakata
Shigehisa Akine
Motohiro Mizuno
author_sort Tomoki Ogoshi
title Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels
title_short Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels
title_full Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels
title_fullStr Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels
title_full_unstemmed Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels
title_sort molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2019-01-01
description Confinement of polymers in nano-spaces can induce unique molecular dynamics and properties. Here the authors show high mass fractionation by the confinement of single polymer chains of poly(ethylene oxide) in the one-dimensional channels of crystalline pillar[5]arene.
url https://doi.org/10.1038/s41467-019-08372-1
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