Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding

Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding

We report the synthesis, characterization, and self-assembly behavior of a 4,4-Difluoro-4-bora-3a,4a-diaza-<i>s</i>-indacene (BODIPY) dye functionalized at the <i>meso</i>-position with a butyric acid group. Various spectroscopic investigations (UV-Vis, emission, and Fourier-...

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Main Authors: Beatriz Matarranz, Angel Sampedro, Constantin G. Daniliuc, Gustavo Fernández
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Crystals
Subjects:
BODIPY dyes
hydrogen bonding
Self-Assembly
weak non-covalent interactions
Online Access:https://www.mdpi.com/2073-4352/8/11/436
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spelling doaj-f7401e3faf75426092f586cd02a40eb92020-11-24T23:20:36ZengMDPI AGCrystals2073-43522018-11-0181143610.3390/cryst8110436cryst8110436Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen BondingBeatriz Matarranz0Angel Sampedro1Constantin G. Daniliuc2Gustavo Fernández3Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße, 40, 48149 Münster, GermanyOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße, 40, 48149 Münster, GermanyOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße, 40, 48149 Münster, GermanyOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße, 40, 48149 Münster, GermanyWe report the synthesis, characterization, and self-assembly behavior of a 4,4-Difluoro-4-bora-3a,4a-diaza-<i>s</i>-indacene (BODIPY) dye functionalized at the <i>meso</i>-position with a butyric acid group. Various spectroscopic investigations (UV-Vis, emission, and Fourier-transform infrared spectroscopy (FTIR) studies) supported by X-ray analysis revealed the formation of self-assembled structures in the solid state with translationally stacked BODIPY units driven by hydrogen bonding between the carboxyl groups.https://www.mdpi.com/2073-4352/8/11/436BODIPY dyeshydrogen bondingSelf-Assemblyweak non-covalent interactions
collection DOAJ
language English
format Article
sources DOAJ
author Beatriz Matarranz
Angel Sampedro
Constantin G. Daniliuc
Gustavo Fernández
spellingShingle Beatriz Matarranz
Angel Sampedro
Constantin G. Daniliuc
Gustavo Fernández
Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding
Crystals
BODIPY dyes
hydrogen bonding
Self-Assembly
weak non-covalent interactions
author_facet Beatriz Matarranz
Angel Sampedro
Constantin G. Daniliuc
Gustavo Fernández
author_sort Beatriz Matarranz
title Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding
title_short Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding
title_full Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding
title_fullStr Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding
title_full_unstemmed Self-Assembly of a Carboxyl-Functionalized BODIPY Dye via Hydrogen Bonding
title_sort self-assembly of a carboxyl-functionalized bodipy dye via hydrogen bonding
publisher MDPI AG
series Crystals
issn 2073-4352
publishDate 2018-11-01
description We report the synthesis, characterization, and self-assembly behavior of a 4,4-Difluoro-4-bora-3a,4a-diaza-<i>s</i>-indacene (BODIPY) dye functionalized at the <i>meso</i>-position with a butyric acid group. Various spectroscopic investigations (UV-Vis, emission, and Fourier-transform infrared spectroscopy (FTIR) studies) supported by X-ray analysis revealed the formation of self-assembled structures in the solid state with translationally stacked BODIPY units driven by hydrogen bonding between the carboxyl groups.
topic BODIPY dyes
hydrogen bonding
Self-Assembly
weak non-covalent interactions
url https://www.mdpi.com/2073-4352/8/11/436
work_keys_str_mv AT beatrizmatarranz selfassemblyofacarboxylfunctionalizedbodipydyeviahydrogenbonding
AT angelsampedro selfassemblyofacarboxylfunctionalizedbodipydyeviahydrogenbonding
AT constantingdaniliuc selfassemblyofacarboxylfunctionalizedbodipydyeviahydrogenbonding
AT gustavofernandez selfassemblyofacarboxylfunctionalizedbodipydyeviahydrogenbonding
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