Direct observation of long-lived cyanide anions in superexcited states

Cyanide anions exist in interstellar space, but the vibrationally or electronically excited states above the electron autodetachment threshold of CN- are assumed to have no contributions to cosmic CN-. Here, the authors report long-lived, superexcited CN- from the dissociative electron attachment to...

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Main Authors: Xiao-Fei Gao, Jing-Chen Xie, Hao Li, Xin Meng, Yong Wu, Shan Xi Tian
Format: Article
Language:English
Published: Nature Publishing Group 2021-02-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-021-00450-0
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spelling doaj-f7cc28aea2104d16bdad4495bdfa3f182021-02-14T12:05:14ZengNature Publishing GroupCommunications Chemistry2399-36692021-02-01411610.1038/s42004-021-00450-0Direct observation of long-lived cyanide anions in superexcited statesXiao-Fei Gao0Jing-Chen Xie1Hao Li2Xin Meng3Yong Wu4Shan Xi Tian5Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemical Physics, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemical Physics, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemical Physics, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemical Physics, University of Science and Technology of ChinaInstitute of Applied Physics and Computational MathematicsHefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemical Physics, University of Science and Technology of ChinaCyanide anions exist in interstellar space, but the vibrationally or electronically excited states above the electron autodetachment threshold of CN- are assumed to have no contributions to cosmic CN-. Here, the authors report long-lived, superexcited CN- from the dissociative electron attachment to cyanogen bromide.https://doi.org/10.1038/s42004-021-00450-0
collection DOAJ
language English
format Article
sources DOAJ
author Xiao-Fei Gao
Jing-Chen Xie
Hao Li
Xin Meng
Yong Wu
Shan Xi Tian
spellingShingle Xiao-Fei Gao
Jing-Chen Xie
Hao Li
Xin Meng
Yong Wu
Shan Xi Tian
Direct observation of long-lived cyanide anions in superexcited states
Communications Chemistry
author_facet Xiao-Fei Gao
Jing-Chen Xie
Hao Li
Xin Meng
Yong Wu
Shan Xi Tian
author_sort Xiao-Fei Gao
title Direct observation of long-lived cyanide anions in superexcited states
title_short Direct observation of long-lived cyanide anions in superexcited states
title_full Direct observation of long-lived cyanide anions in superexcited states
title_fullStr Direct observation of long-lived cyanide anions in superexcited states
title_full_unstemmed Direct observation of long-lived cyanide anions in superexcited states
title_sort direct observation of long-lived cyanide anions in superexcited states
publisher Nature Publishing Group
series Communications Chemistry
issn 2399-3669
publishDate 2021-02-01
description Cyanide anions exist in interstellar space, but the vibrationally or electronically excited states above the electron autodetachment threshold of CN- are assumed to have no contributions to cosmic CN-. Here, the authors report long-lived, superexcited CN- from the dissociative electron attachment to cyanogen bromide.
url https://doi.org/10.1038/s42004-021-00450-0
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AT jingchenxie directobservationoflonglivedcyanideanionsinsuperexcitedstates
AT haoli directobservationoflonglivedcyanideanionsinsuperexcitedstates
AT xinmeng directobservationoflonglivedcyanideanionsinsuperexcitedstates
AT yongwu directobservationoflonglivedcyanideanionsinsuperexcitedstates
AT shanxitian directobservationoflonglivedcyanideanionsinsuperexcitedstates
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