Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety
A series of novel 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone framework (4a-f) were synthesized through a four-step reaction starting from the reduction of nitro derivatives of 1, 8-dioxo-octahydroxanthenes. The resulting aminoxanthenes converted to thiourea derivatives via...
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2017-10-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
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| Online Access: | http://www.ijcce.ac.ir/article_24714_83da0648f883d15c460a03bf9448353e.pdf |
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doaj-f8ef1ead76f541e1a70b0324c93e3cba2020-11-25T02:59:54ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862017-10-0136591624714Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moietyMaryam Robati0Dadkhoda Ghazanfari1Mohammad Reza Islami2Kazem Saidi3Department of Chemistry, Faculty of Science, Kerman Branch, Islamic Azad University, P.O. Box 7635131167 Kerman, I.R. IRANDepartment of Chemistry, Faculty of Science, Kerman Branch, Islamic Azad University, P.O. Box 7635131167 Kerman, I.R. IRANDepartment of Chemistry, Shahid Bahonar University of Kerman, P.O. Box 76169 14111 Kerman, I.R. IRANDepartment of Chemistry, Shahid Bahonar University of Kerman, P.O. Box 76169 14111 Kerman, I.R. IRANA series of novel 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone framework (4a-f) were synthesized through a four-step reaction starting from the reduction of nitro derivatives of 1, 8-dioxo-octahydroxanthenes. The resulting aminoxanthenes converted to thiourea derivatives via their reaction with methyl isothiocyanate. The final products were synthesized through the reaction of thiourea derivatives with dialkylacetylene dicarboxylates. All of the steps were carried out under easy and mild reaction conditions in the absence of expensive catalysts or esoteric starting materials. The structures of compounds 3a-c and the final products were characterized according to their physical constants, spectral data such as NMR, IR spectra and also elemental analysis.http://www.ijcce.ac.ir/article_24714_83da0648f883d15c460a03bf9448353e.pdf1, 8-dioxo-octahydroxanthene4-thiazolidinonedialkyl acetylene dicarboxylatedimedone1, 3-cyclohexanedione |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Maryam Robati Dadkhoda Ghazanfari Mohammad Reza Islami Kazem Saidi |
| spellingShingle |
Maryam Robati Dadkhoda Ghazanfari Mohammad Reza Islami Kazem Saidi Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety Iranian Journal of Chemistry & Chemical Engineering 1, 8-dioxo-octahydroxanthene 4-thiazolidinone dialkyl acetylene dicarboxylate dimedone 1, 3-cyclohexanedione |
| author_facet |
Maryam Robati Dadkhoda Ghazanfari Mohammad Reza Islami Kazem Saidi |
| author_sort |
Maryam Robati |
| title |
Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety |
| title_short |
Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety |
| title_full |
Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety |
| title_fullStr |
Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety |
| title_full_unstemmed |
Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety |
| title_sort |
synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety |
| publisher |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| series |
Iranian Journal of Chemistry & Chemical Engineering |
| issn |
1021-9986 1021-9986 |
| publishDate |
2017-10-01 |
| description |
A series of novel 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone framework (4a-f) were synthesized through a four-step reaction starting from the reduction of nitro derivatives of 1, 8-dioxo-octahydroxanthenes. The resulting aminoxanthenes converted to thiourea derivatives via their reaction with methyl isothiocyanate. The final products were synthesized through the reaction of thiourea derivatives with dialkylacetylene dicarboxylates. All of the steps were carried out under easy and mild reaction conditions in the absence of expensive catalysts or esoteric starting materials. The structures of compounds 3a-c and the final products were characterized according to their physical constants, spectral data such as NMR, IR spectra and also elemental analysis. |
| topic |
1, 8-dioxo-octahydroxanthene 4-thiazolidinone dialkyl acetylene dicarboxylate dimedone 1, 3-cyclohexanedione |
| url |
http://www.ijcce.ac.ir/article_24714_83da0648f883d15c460a03bf9448353e.pdf |
| work_keys_str_mv |
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