Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes

Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes

A new symmetric bidentate Schiff base N, N′ bis(4-fluorobenzal-dehydene)-1,2-diaminoethane(L) and its complexes with general formula MLX2 (M= Zn(II), Cd(II) and Hg(II) and X=chloride, bromide, iodide, thiocyanate and azide) have been prepared. The ligand and complexes have been established by microa...

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Main Authors: M. Montazerozohori, S. Khani, S. Joohari, S. A. Musavi
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/952926
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spelling doaj-f97204c137a9449f89e3c50d3806b50c2020-11-24T20:41:24ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102012-01-01942483249210.1155/2012/952926Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated ComplexesM. Montazerozohori0S. Khani1S. Joohari2S. A. Musavi3Department of Chemistry, Yasouj University, Yasouj, 7591874831, IranDepartment of Chemistry, Yasouj University, Yasouj, 7591874831, IranDepartment of Basic Science, Yasouj Branch, Islamic Azad University, Yasouj, IranDepartment of Chemistry, Yasouj University, Yasouj, 7591874831, IranA new symmetric bidentate Schiff base N, N′ bis(4-fluorobenzal-dehydene)-1,2-diaminoethane(L) and its complexes with general formula MLX2 (M= Zn(II), Cd(II) and Hg(II) and X=chloride, bromide, iodide, thiocyanate and azide) have been prepared. The ligand and complexes have been established by microanalysis, electronic, FT-IR, 1H and 13C NMR spectra, and by molar conductivity measurements. All compounds are non-electrolytes in chloroform or DMSO-d6. The thermal behavior of the complexes shows weight loss by decomposition of the anions and ligand segments in the subsequent steps. Some activation thermodynamic parameters such as E*, ∆H*, ∆S* and ∆G* were calculated from thermal analysis.http://dx.doi.org/10.1155/2012/952926
collection DOAJ
language English
format Article
sources DOAJ
author M. Montazerozohori
S. Khani
S. Joohari
S. A. Musavi
spellingShingle M. Montazerozohori
S. Khani
S. Joohari
S. A. Musavi
Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes
E-Journal of Chemistry
author_facet M. Montazerozohori
S. Khani
S. Joohari
S. A. Musavi
author_sort M. Montazerozohori
title Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes
title_short Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes
title_full Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes
title_fullStr Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes
title_full_unstemmed Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes
title_sort synthesis, spectral and thermal behavior of some new four coordinated complexes
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2012-01-01
description A new symmetric bidentate Schiff base N, N′ bis(4-fluorobenzal-dehydene)-1,2-diaminoethane(L) and its complexes with general formula MLX2 (M= Zn(II), Cd(II) and Hg(II) and X=chloride, bromide, iodide, thiocyanate and azide) have been prepared. The ligand and complexes have been established by microanalysis, electronic, FT-IR, 1H and 13C NMR spectra, and by molar conductivity measurements. All compounds are non-electrolytes in chloroform or DMSO-d6. The thermal behavior of the complexes shows weight loss by decomposition of the anions and ligand segments in the subsequent steps. Some activation thermodynamic parameters such as E*, ∆H*, ∆S* and ∆G* were calculated from thermal analysis.
url http://dx.doi.org/10.1155/2012/952926
work_keys_str_mv AT mmontazerozohori synthesisspectralandthermalbehaviorofsomenewfourcoordinatedcomplexes
AT skhani synthesisspectralandthermalbehaviorofsomenewfourcoordinatedcomplexes
AT sjoohari synthesisspectralandthermalbehaviorofsomenewfourcoordinatedcomplexes
AT samusavi synthesisspectralandthermalbehaviorofsomenewfourcoordinatedcomplexes
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