Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
A new Pb(II) complex, [Pb(bp)2(btfa)2] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions...
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doaj-f996dce2d9344bc2ba6295deb11645bf2020-11-25T02:25:21ZengHindawi LimitedJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/159125159125Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate LigandsSaeideh Hosseini0Farzin Marandi1Ertan Şahin2Seyid Javad Musevi3Department of Chemistry, Islamic Azad University, Karaj Branch, Karaj, IranDepartment of Chemistry, Payame Noor University, Tehran 19395-3697, IranDepartment of Chemistry, Atatürk University, 25240 Erzurum, TurkeyDepartment of Chemistry, Shahid Beheshti Technical Faculty, Technical and Vocational University, Urmia, IranA new Pb(II) complex, [Pb(bp)2(btfa)2] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically “inactive” electron lone pair with holodirected coordination spheres. In solid state, there are π⋯π, C–H⋯F, C–H⋯O, and F⋯F interactions between adjacent units to generate 3D supramolecular structure.http://dx.doi.org/10.1155/2013/159125 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Saeideh Hosseini Farzin Marandi Ertan Şahin Seyid Javad Musevi |
spellingShingle |
Saeideh Hosseini Farzin Marandi Ertan Şahin Seyid Javad Musevi Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands Journal of Chemistry |
author_facet |
Saeideh Hosseini Farzin Marandi Ertan Şahin Seyid Javad Musevi |
author_sort |
Saeideh Hosseini |
title |
Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands |
title_short |
Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands |
title_full |
Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands |
title_fullStr |
Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands |
title_full_unstemmed |
Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands |
title_sort |
synthesis, crystal structure and thermal properties of lead(ii) complex with bathophenanthroline and benzoyltrifluoroacetonate ligands |
publisher |
Hindawi Limited |
series |
Journal of Chemistry |
issn |
2090-9063 2090-9071 |
publishDate |
2013-01-01 |
description |
A new Pb(II) complex, [Pb(bp)2(btfa)2] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically “inactive” electron lone pair with holodirected coordination spheres. In solid state, there are π⋯π, C–H⋯F, C–H⋯O, and F⋯F interactions between adjacent units to generate 3D supramolecular structure. |
url |
http://dx.doi.org/10.1155/2013/159125 |
work_keys_str_mv |
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