Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands

Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands

A new Pb(II) complex, [Pb(bp)2(btfa)2]  1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions...

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Main Authors: Saeideh Hosseini, Farzin Marandi, Ertan Şahin, Seyid Javad Musevi
Format: Article
Language:English
Published: Hindawi Limited 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/159125
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spelling doaj-f996dce2d9344bc2ba6295deb11645bf2020-11-25T02:25:21ZengHindawi LimitedJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/159125159125Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate LigandsSaeideh Hosseini0Farzin Marandi1Ertan Şahin2Seyid Javad Musevi3Department of Chemistry, Islamic Azad University, Karaj Branch, Karaj, IranDepartment of Chemistry, Payame Noor University, Tehran 19395-3697, IranDepartment of Chemistry, Atatürk University, 25240 Erzurum, TurkeyDepartment of Chemistry, Shahid Beheshti Technical Faculty, Technical and Vocational University, Urmia, IranA new Pb(II) complex, [Pb(bp)2(btfa)2]  1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically “inactive” electron lone pair with holodirected coordination spheres. In solid state, there are π⋯π, C–H⋯F, C–H⋯O, and F⋯F interactions between adjacent units to generate 3D supramolecular structure.http://dx.doi.org/10.1155/2013/159125
collection DOAJ
language English
format Article
sources DOAJ
author Saeideh Hosseini
Farzin Marandi
Ertan Şahin
Seyid Javad Musevi
spellingShingle Saeideh Hosseini
Farzin Marandi
Ertan Şahin
Seyid Javad Musevi
Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
Journal of Chemistry
author_facet Saeideh Hosseini
Farzin Marandi
Ertan Şahin
Seyid Javad Musevi
author_sort Saeideh Hosseini
title Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
title_short Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
title_full Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
title_fullStr Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
title_full_unstemmed Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
title_sort synthesis, crystal structure and thermal properties of lead(ii) complex with bathophenanthroline and benzoyltrifluoroacetonate ligands
publisher Hindawi Limited
series Journal of Chemistry
issn 2090-9063
2090-9071
publishDate 2013-01-01
description A new Pb(II) complex, [Pb(bp)2(btfa)2]  1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically “inactive” electron lone pair with holodirected coordination spheres. In solid state, there are π⋯π, C–H⋯F, C–H⋯O, and F⋯F interactions between adjacent units to generate 3D supramolecular structure.
url http://dx.doi.org/10.1155/2013/159125
work_keys_str_mv AT saeidehhosseini synthesiscrystalstructureandthermalpropertiesofleadiicomplexwithbathophenanthrolineandbenzoyltrifluoroacetonateligands
AT farzinmarandi synthesiscrystalstructureandthermalpropertiesofleadiicomplexwithbathophenanthrolineandbenzoyltrifluoroacetonateligands
AT ertansahin synthesiscrystalstructureandthermalpropertiesofleadiicomplexwithbathophenanthrolineandbenzoyltrifluoroacetonateligands
AT seyidjavadmusevi synthesiscrystalstructureandthermalpropertiesofleadiicomplexwithbathophenanthrolineandbenzoyltrifluoroacetonateligands
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