2-Carboxyquinolinium–2,4,6-trinitrobenzenesulfonate–quinolinium-2-carboxylate (1/1/1)
The structure of the title adduct compound, C10H8NO2+·C6H2N3O9S−·C10H7NO2, from the reaction of 2,4,6-trinitrobenzenesulfonic acid (picrylsulfonic acid) with quinoline-2-carboxylic acid (quinaldic acid) in 2-propanol–water, has been determined at 130 (...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807062757 |
| Summary: | The structure of the title adduct compound, C10H8NO2+·C6H2N3O9S−·C10H7NO2, from the reaction of 2,4,6-trinitrobenzenesulfonic acid (picrylsulfonic acid) with quinoline-2-carboxylic acid (quinaldic acid) in 2-propanol–water, has been determined at 130 (2) K. The cation and the adduct species form a twisted cyclic hydrogen-bonded R22(10) pseudo-dimer which is extended into a one-dimensional chain structure through short head-to-tail carboxylic acid O—H...Ocarboxyl associations [O...O = 2.4711 (19) Å]. The picrylsulfonate anions are attached peripherally by single N—H...Osulfonate hydrogen bonds [N...O = 2.8643 (19) Å]. |
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| ISSN: | 1600-5368 |