Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based Electrolytes
Samples of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) were prepared by solid-state synthesis. Additionally, the sample with nominal composition La0.95Bi0.05Mn0.7Cu0.3O3+δ was obtained using citrate-nitrate method. It was determined by X-ray diffraction analysis that the compounds have rhombohedral (space...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2018-07-01
|
Series: | Chimica Techno Acta |
Subjects: | |
Online Access: | https://journals.urfu.ru/index.php/chimtech/article/view/3282 |
id |
doaj-fadaf8ae2ce346698a276850f11c54a8 |
---|---|
record_format |
Article |
spelling |
doaj-fadaf8ae2ce346698a276850f11c54a82020-11-24T21:00:25ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina Chimica Techno Acta2409-56132411-14142018-07-015210911610.15826/chimtech.2018.5.3.032737Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based ElectrolytesO. S. Kaimieva0V. V. Danilova1E. S. Buyanova2S. A. Petrova3I. V. Nikolaenko4Ural Federal University, EkaterinburgUral Federal University, EkaterinburgUral Federal University, EkaterinburgInstitute of Metallurgy, Ural Branch of Russian Academy of Sciences, EkaterinburgInstitute of Solid State Chemistry, Ural Branch of Russian Academy of Sciences; Ural Federal University, EkaterinburgSamples of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) were prepared by solid-state synthesis. Additionally, the sample with nominal composition La0.95Bi0.05Mn0.7Cu0.3O3+δ was obtained using citrate-nitrate method. It was determined by X-ray diffraction analysis that the compounds have rhombohedral (space group R-3c) or orthorhombic (space group Pbnm) structure, depending on the composition. Single-phase compounds are synthesized at у=0.1; 0.2. The investigation using scanning electron microscope showed that the grain sizes for the samples sintered using different techniques are close to each other because of the high calcination temperature. For the sample with orthorhombic structure the phase transition into rhombohedral one was found around 390 °С by means of dilatometry. Thermal expansion coefficient of the sample La0.95Bi0.05Mn0.7Cu0.3O3+δ is equal to 6·10-6 K-1 (T < 390 °C) and 15·10-6 K-1 (T > 390 °C). The composite materials of substituted lanthanum manganites with Bi4V1.7Fe0.3O11-δ and Bi7Nb1.8Zr0.2O15.5-δ solid electrolytes were obtained at 650 °C. The electrical conductivity values for the latter one are by three orders of magnitude higher than for pure bismuth niobate.https://journals.urfu.ru/index.php/chimtech/article/view/3282lanthanum manganiteperovskite-like structuremixed conductorcomposite |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
O. S. Kaimieva V. V. Danilova E. S. Buyanova S. A. Petrova I. V. Nikolaenko |
spellingShingle |
O. S. Kaimieva V. V. Danilova E. S. Buyanova S. A. Petrova I. V. Nikolaenko Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based Electrolytes Chimica Techno Acta lanthanum manganite perovskite-like structure mixed conductor composite |
author_facet |
O. S. Kaimieva V. V. Danilova E. S. Buyanova S. A. Petrova I. V. Nikolaenko |
author_sort |
O. S. Kaimieva |
title |
Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based Electrolytes |
title_short |
Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based Electrolytes |
title_full |
Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based Electrolytes |
title_fullStr |
Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based Electrolytes |
title_full_unstemmed |
Preparation, Structure and Physicochemical Properties of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) and Composites with Bi2O3-Based Electrolytes |
title_sort |
preparation, structure and physicochemical properties of la0.95bi0.05mn1-ycuyo3+δ (у=0.1-0.4) and composites with bi2o3-based electrolytes |
publisher |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
series |
Chimica Techno Acta |
issn |
2409-5613 2411-1414 |
publishDate |
2018-07-01 |
description |
Samples of La0.95Bi0.05Mn1-yCuyO3+δ (у=0.1-0.4) were prepared by solid-state synthesis. Additionally, the sample with nominal composition La0.95Bi0.05Mn0.7Cu0.3O3+δ was obtained using citrate-nitrate method. It was determined by X-ray diffraction analysis that the compounds have rhombohedral (space group R-3c) or orthorhombic (space group Pbnm) structure, depending on the composition. Single-phase compounds are synthesized at у=0.1; 0.2. The investigation using scanning electron microscope showed that the grain sizes for the samples sintered using different techniques are close to each other because of the high calcination temperature. For the sample with orthorhombic structure the phase transition into rhombohedral one was found around 390 °С by means of dilatometry. Thermal expansion coefficient of the sample La0.95Bi0.05Mn0.7Cu0.3O3+δ is equal to 6·10-6 K-1 (T < 390 °C) and 15·10-6 K-1 (T > 390 °C). The composite materials of substituted lanthanum manganites with Bi4V1.7Fe0.3O11-δ and Bi7Nb1.8Zr0.2O15.5-δ solid electrolytes were obtained at 650 °C. The electrical conductivity values for the latter one are by three orders of magnitude higher than for pure bismuth niobate. |
topic |
lanthanum manganite perovskite-like structure mixed conductor composite |
url |
https://journals.urfu.ru/index.php/chimtech/article/view/3282 |
work_keys_str_mv |
AT oskaimieva preparationstructureandphysicochemicalpropertiesofla095bi005mn1ycuyo3du0104andcompositeswithbi2o3basedelectrolytes AT vvdanilova preparationstructureandphysicochemicalpropertiesofla095bi005mn1ycuyo3du0104andcompositeswithbi2o3basedelectrolytes AT esbuyanova preparationstructureandphysicochemicalpropertiesofla095bi005mn1ycuyo3du0104andcompositeswithbi2o3basedelectrolytes AT sapetrova preparationstructureandphysicochemicalpropertiesofla095bi005mn1ycuyo3du0104andcompositeswithbi2o3basedelectrolytes AT ivnikolaenko preparationstructureandphysicochemicalpropertiesofla095bi005mn1ycuyo3du0104andcompositeswithbi2o3basedelectrolytes |
_version_ |
1716779732447526912 |