Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups
A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their...
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doaj-fb6f243c82ca420496f548e9f080d0b72020-11-25T00:17:53ZengMDPI AGMolecules1420-30492014-12-011912210222103310.3390/molecules191221022molecules191221022Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic GroupsKrzysztof R. Idzik0Karsten Nödler1Friedrich Maier2Tobias Licha3Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyDepartment Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyDepartment Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyDepartment Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyA series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.http://www.mdpi.com/1420-3049/19/12/21022sulfonic acid estersprimary alcoholsphenolsacylationreaction kinetics |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Krzysztof R. Idzik Karsten Nödler Friedrich Maier Tobias Licha |
spellingShingle |
Krzysztof R. Idzik Karsten Nödler Friedrich Maier Tobias Licha Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups Molecules sulfonic acid esters primary alcohols phenols acylation reaction kinetics |
author_facet |
Krzysztof R. Idzik Karsten Nödler Friedrich Maier Tobias Licha |
author_sort |
Krzysztof R. Idzik |
title |
Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups |
title_short |
Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups |
title_full |
Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups |
title_fullStr |
Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups |
title_full_unstemmed |
Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups |
title_sort |
efficient synthesis and reaction kinetics of readily water soluble esters containing sulfonic groups |
publisher |
MDPI AG |
series |
Molecules |
issn |
1420-3049 |
publishDate |
2014-12-01 |
description |
A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR. |
topic |
sulfonic acid esters primary alcohols phenols acylation reaction kinetics |
url |
http://www.mdpi.com/1420-3049/19/12/21022 |
work_keys_str_mv |
AT krzysztofridzik efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups AT karstennodler efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups AT friedrichmaier efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups AT tobiaslicha efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups |
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1725377835960369152 |