Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups

A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their...

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Main Authors:	Krzysztof R. Idzik, Karsten Nödler, Friedrich Maier, Tobias Licha
Format:	Article
Language:	English
Published:	MDPI AG 2014-12-01
Series:	Molecules
Subjects:	sulfonic acid esters primary alcohols phenols acylation reaction kinetics
Online Access:	http://www.mdpi.com/1420-3049/19/12/21022

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spelling	doaj-fb6f243c82ca420496f548e9f080d0b72020-11-25T00:17:53ZengMDPI AGMolecules1420-30492014-12-011912210222103310.3390/molecules191221022molecules191221022Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic GroupsKrzysztof R. Idzik0Karsten Nödler1Friedrich Maier2Tobias Licha3Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyDepartment Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyDepartment Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyDepartment Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, GermanyA series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.http://www.mdpi.com/1420-3049/19/12/21022sulfonic acid estersprimary alcoholsphenolsacylationreaction kinetics
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Krzysztof R. Idzik Karsten Nödler Friedrich Maier Tobias Licha
spellingShingle	Krzysztof R. Idzik Karsten Nödler Friedrich Maier Tobias Licha Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups Molecules sulfonic acid esters primary alcohols phenols acylation reaction kinetics
author_facet	Krzysztof R. Idzik Karsten Nödler Friedrich Maier Tobias Licha
author_sort	Krzysztof R. Idzik
title	Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups
title_short	Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups
title_full	Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups
title_fullStr	Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups
title_full_unstemmed	Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups
title_sort	efficient synthesis and reaction kinetics of readily water soluble esters containing sulfonic groups
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2014-12-01
description	A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.
topic	sulfonic acid esters primary alcohols phenols acylation reaction kinetics
url	http://www.mdpi.com/1420-3049/19/12/21022
work_keys_str_mv	AT krzysztofridzik efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups AT karstennodler efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups AT friedrichmaier efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups AT tobiaslicha efficientsynthesisandreactionkineticsofreadilywatersolubleesterscontainingsulfonicgroups
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Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups

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