rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol

rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol

A novel Schiff base compound, C20H27NO2, was obtained by a condensation of rimantadine and 2-hydroxy-4-methoxybenzaldehyde. An intramolecular O—H...N hydrogen bond supports the phenol–imine tautomeric form. The adamantane and iminomethyl-4-methoxyphenol units are arranged...

Full description

Bibliographic Details
Main Authors: Xu-Dong Jin, Hai-Bo Wang, Yue-Hong Jin
Format: Article
Language:English
Published: International Union of Crystallography 2011-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811030522
id doaj-fbe346d302794fb993581d061f01d8b4
record_format Article
spelling doaj-fbe346d302794fb993581d061f01d8b42020-11-24T22:09:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679o2233o223310.1107/S1600536811030522rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenolXu-Dong JinHai-Bo WangYue-Hong JinA novel Schiff base compound, C20H27NO2, was obtained by a condensation of rimantadine and 2-hydroxy-4-methoxybenzaldehyde. An intramolecular O—H...N hydrogen bond supports the phenol–imine tautomeric form. The adamantane and iminomethyl-4-methoxyphenol units are arranged in a folded conformation [C—N—C—C torsion angle = 110.9 (3)°]. In the crystal, highly hydrophobic adamantane moieties are inserted between the iminomethyl-4-methoxyphenol units in a sandwich-like arrangement along the c axis. http://scripts.iucr.org/cgi-bin/paper?S1600536811030522
collection DOAJ
language English
format Article
sources DOAJ
author Xu-Dong Jin
Hai-Bo Wang
Yue-Hong Jin
spellingShingle Xu-Dong Jin
Hai-Bo Wang
Yue-Hong Jin
rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol
Acta Crystallographica Section E
author_facet Xu-Dong Jin
Hai-Bo Wang
Yue-Hong Jin
author_sort Xu-Dong Jin
title rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol
title_short rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol
title_full rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol
title_fullStr rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol
title_full_unstemmed rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol
title_sort rac-2-{[1-(1-adamantyl)ethyl]iminomethyl}-5-methoxyphenol
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-09-01
description A novel Schiff base compound, C20H27NO2, was obtained by a condensation of rimantadine and 2-hydroxy-4-methoxybenzaldehyde. An intramolecular O—H...N hydrogen bond supports the phenol–imine tautomeric form. The adamantane and iminomethyl-4-methoxyphenol units are arranged in a folded conformation [C—N—C—C torsion angle = 110.9 (3)°]. In the crystal, highly hydrophobic adamantane moieties are inserted between the iminomethyl-4-methoxyphenol units in a sandwich-like arrangement along the c axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811030522
work_keys_str_mv AT xudongjin rac211adamantylethyliminomethyl5methoxyphenol
AT haibowang rac211adamantylethyliminomethyl5methoxyphenol
AT yuehongjin rac211adamantylethyliminomethyl5methoxyphenol
_version_ 1725811052547932160

Similar Items