rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol
A novel Schiff base compound, C20H27NO2, was obtained by a condensation of rimantadine and 2-hydroxy-4-methoxybenzaldehyde. An intramolecular O—H...N hydrogen bond supports the phenol–imine tautomeric form. The adamantane and iminomethyl-4-methoxyphenol units are arranged...
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International Union of Crystallography
2011-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811030522 |
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doaj-fbe346d302794fb993581d061f01d8b42020-11-24T22:09:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679o2233o223310.1107/S1600536811030522rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenolXu-Dong JinHai-Bo WangYue-Hong JinA novel Schiff base compound, C20H27NO2, was obtained by a condensation of rimantadine and 2-hydroxy-4-methoxybenzaldehyde. An intramolecular O—H...N hydrogen bond supports the phenol–imine tautomeric form. The adamantane and iminomethyl-4-methoxyphenol units are arranged in a folded conformation [C—N—C—C torsion angle = 110.9 (3)°]. In the crystal, highly hydrophobic adamantane moieties are inserted between the iminomethyl-4-methoxyphenol units in a sandwich-like arrangement along the c axis. http://scripts.iucr.org/cgi-bin/paper?S1600536811030522 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Xu-Dong Jin Hai-Bo Wang Yue-Hong Jin |
spellingShingle |
Xu-Dong Jin Hai-Bo Wang Yue-Hong Jin rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol Acta Crystallographica Section E |
author_facet |
Xu-Dong Jin Hai-Bo Wang Yue-Hong Jin |
author_sort |
Xu-Dong Jin |
title |
rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol |
title_short |
rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol |
title_full |
rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol |
title_fullStr |
rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol |
title_full_unstemmed |
rac-2-{[1-(1-Adamantyl)ethyl]iminomethyl}-5-methoxyphenol |
title_sort |
rac-2-{[1-(1-adamantyl)ethyl]iminomethyl}-5-methoxyphenol |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-09-01 |
description |
A novel Schiff base compound, C20H27NO2, was obtained by a condensation of rimantadine and 2-hydroxy-4-methoxybenzaldehyde. An intramolecular O—H...N hydrogen bond supports the phenol–imine tautomeric form. The adamantane and iminomethyl-4-methoxyphenol units are arranged in a folded conformation [C—N—C—C torsion angle = 110.9 (3)°]. In the crystal, highly hydrophobic adamantane moieties are inserted between the iminomethyl-4-methoxyphenol units in a sandwich-like arrangement along the c axis. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811030522 |
work_keys_str_mv |
AT xudongjin rac211adamantylethyliminomethyl5methoxyphenol AT haibowang rac211adamantylethyliminomethyl5methoxyphenol AT yuehongjin rac211adamantylethyliminomethyl5methoxyphenol |
_version_ |
1725811052547932160 |