Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)

Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)

The title compound, [Cu(CH3COO)2(C7H9NO)2], is a monomeric complex with an octahedral geometry. The CuII atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyridin-2-yl)ethan...

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Main Authors: Katja Lapanje, Ivan Leban, Nina Lah
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812015747
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spelling doaj-fc322c4b62af47f2a28b8bcb5a8872152020-11-24T21:52:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m599m59910.1107/S1600536812015747Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)Katja LapanjeIvan LebanNina LahThe title compound, [Cu(CH3COO)2(C7H9NO)2], is a monomeric complex with an octahedral geometry. The CuII atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyridin-2-yl)ethanol is coordinated as a bidentate ligand involving the endocyclic N atom and the hydroxy O atom of the ligand side chain. An intramolecular hydrogen bond is observed between the hydroxy O atom and the non-coordinated acetate O atom. No classical intermolecular hydrogen-bond contacts were observed. However, the crystal packing is effected by C—H...O interactions, which link the mononuclear entities into layers parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S1600536812015747
collection DOAJ
language English
format Article
sources DOAJ
author Katja Lapanje
Ivan Leban
Nina Lah
spellingShingle Katja Lapanje
Ivan Leban
Nina Lah
Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)
Acta Crystallographica Section E
author_facet Katja Lapanje
Ivan Leban
Nina Lah
author_sort Katja Lapanje
title Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)
title_short Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)
title_full Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)
title_fullStr Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)
title_full_unstemmed Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ2N,O]copper(II)
title_sort bis(acetato-κo)bis[2-(pyridin-2-yl)ethanol-κ2n,o]copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description The title compound, [Cu(CH3COO)2(C7H9NO)2], is a monomeric complex with an octahedral geometry. The CuII atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyridin-2-yl)ethanol is coordinated as a bidentate ligand involving the endocyclic N atom and the hydroxy O atom of the ligand side chain. An intramolecular hydrogen bond is observed between the hydroxy O atom and the non-coordinated acetate O atom. No classical intermolecular hydrogen-bond contacts were observed. However, the crystal packing is effected by C—H...O interactions, which link the mononuclear entities into layers parallel to the bc plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812015747
work_keys_str_mv AT katjalapanje bisacetatoamp954obis2pyridin2ylethanolamp9542nocopperii
AT ivanleban bisacetatoamp954obis2pyridin2ylethanolamp9542nocopperii
AT ninalah bisacetatoamp954obis2pyridin2ylethanolamp9542nocopperii
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