Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(2,2′-bipyridine-κ2N,N′)copper(I)] bis(tetrafluoroborate)

Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(2,2′-bipyridine-κ2N,N′)copper(I)] bis(tetrafluoroborate)

The centrosymmetric title compound, [Cu2(C10H8N2)2(C25H22P2)2](BF4)2, consists of discrete dinuclear cations and tetrafluoroborate anions. The two CuI centers are bridged by the phosphine ligands to form an eight-membered ring. The CuI center exhibits a tetrahedral coordination as it is chelated by...

Full description

Bibliographic Details
Main Authors: Shouwen Jin, Daqi Wang
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809038252
Description
Summary:The centrosymmetric title compound, [Cu2(C10H8N2)2(C25H22P2)2](BF4)2, consists of discrete dinuclear cations and tetrafluoroborate anions. The two CuI centers are bridged by the phosphine ligands to form an eight-membered ring. The CuI center exhibits a tetrahedral coordination as it is chelated by the N-heterocycle.
ISSN:1600-5368

Similar Items