Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)

Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)

The structure of a salt of diprotonated endo-3-aminotropane crystallized with a copper(II) anionic cluster is reported, viz. (C8H18N2)[CuCl3(NO3)(H2O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensional structur...

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Main Authors: Sergey N. Britvin, Andrey M. Rumyantsev
Format: Article
Language:English
Published: International Union of Crystallography 2017-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
tropane
nitrogen heterocycle
copper(II)complex
isomer separation
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017014633
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spelling doaj-fd0d7611399946b7bad0526daafef39d2020-11-25T00:28:48ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-11-0173111712171510.1107/S2056989017014633cq2021Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)Sergey N. Britvin0Andrey M. Rumyantsev1Department of Crystallography, Saint Petersburg State University, Universitetskaya Nab. 7/9, 199034 St Petersburg, Russian FederationDepartment of Genetics and Biotechnology, Saint Petersburg State University, Universitetskaya Nab. 7/9, 199034 St Petersburg, Russian FederationThe structure of a salt of diprotonated endo-3-aminotropane crystallized with a copper(II) anionic cluster is reported, viz. (C8H18N2)[CuCl3(NO3)(H2O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensional structure held together by a network of intermolecular N—H...O, O—H...Cl and N—H...Cl hydrogen-bonding interactions. Selective crystallization of the title compound can be considered as a simple method for the separation of the exo and endo isomers of 3-aminotropane.http://scripts.iucr.org/cgi-bin/paper?S2056989017014633crystal structuretropanenitrogen heterocyclecopper(II)complexisomer separation
collection DOAJ
language English
format Article
sources DOAJ
author Sergey N. Britvin
Andrey M. Rumyantsev
spellingShingle Sergey N. Britvin
Andrey M. Rumyantsev
Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
tropane
nitrogen heterocycle
copper(II)complex
isomer separation
author_facet Sergey N. Britvin
Andrey M. Rumyantsev
author_sort Sergey N. Britvin
title Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)
title_short Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)
title_full Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)
title_fullStr Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)
title_full_unstemmed Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)
title_sort crystal structure of (1r,5s)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2017-11-01
description The structure of a salt of diprotonated endo-3-aminotropane crystallized with a copper(II) anionic cluster is reported, viz. (C8H18N2)[CuCl3(NO3)(H2O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensional structure held together by a network of intermolecular N—H...O, O—H...Cl and N—H...Cl hydrogen-bonding interactions. Selective crystallization of the title compound can be considered as a simple method for the separation of the exo and endo isomers of 3-aminotropane.
topic crystal structure
tropane
nitrogen heterocycle
copper(II)complex
isomer separation
url http://scripts.iucr.org/cgi-bin/paper?S2056989017014633
work_keys_str_mv AT sergeynbritvin crystalstructureof1r5sendo8methyl8azoniabicyclo321oct3ylammoniumaquatrichloridonitratocopperii
AT andreymrumyantsev crystalstructureof1r5sendo8methyl8azoniabicyclo321oct3ylammoniumaquatrichloridonitratocopperii
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