Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)

Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)

The asymmetric unit of the title CoII complex, [Co(C8H8NO2)2(C6H6N2O)2(H2O)2], contains two half complex molecules with similar structures. The CoII atoms are each located on an inversion center and each is coordinated by two 4-methylaminobenzoate (PMAB), two nicotinamide (NA) ligands and two water...

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Main Authors: Hacali Necefoğlu, Özgür Aybirdi, Barış Tercan, Emel Ermiş, Tuncer Hökelek
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810010706
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spelling doaj-fd8a6d28873044c79513f89966e6af102020-11-25T02:15:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m448m44910.1107/S1600536810010706Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)Hacali NecefoğluÖzgür AybirdiBarış TercanEmel ErmişTuncer HökelekThe asymmetric unit of the title CoII complex, [Co(C8H8NO2)2(C6H6N2O)2(H2O)2], contains two half complex molecules with similar structures. The CoII atoms are each located on an inversion center and each is coordinated by two 4-methylaminobenzoate (PMAB), two nicotinamide (NA) ligands and two water molecules in a distorted octahedral coordination. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)°, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)°. In the crystal structure, intermolecular O—H...O and N—H...O hydrogen bonds link the molecules into a supramolecular structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810010706
collection DOAJ
language English
format Article
sources DOAJ
author Hacali Necefoğlu
Özgür Aybirdi
Barış Tercan
Emel Ermiş
Tuncer Hökelek
spellingShingle Hacali Necefoğlu
Özgür Aybirdi
Barış Tercan
Emel Ermiş
Tuncer Hökelek
Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)
Acta Crystallographica Section E
author_facet Hacali Necefoğlu
Özgür Aybirdi
Barış Tercan
Emel Ermiş
Tuncer Hökelek
author_sort Hacali Necefoğlu
title Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)
title_short Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)
title_full Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)
title_fullStr Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)
title_full_unstemmed Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN1)cobalt(II)
title_sort diaquabis(4-methylaminobenzoato-κo)bis(nicotinamide-κn1)cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-04-01
description The asymmetric unit of the title CoII complex, [Co(C8H8NO2)2(C6H6N2O)2(H2O)2], contains two half complex molecules with similar structures. The CoII atoms are each located on an inversion center and each is coordinated by two 4-methylaminobenzoate (PMAB), two nicotinamide (NA) ligands and two water molecules in a distorted octahedral coordination. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)°, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)°. In the crystal structure, intermolecular O—H...O and N—H...O hydrogen bonds link the molecules into a supramolecular structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810010706
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AT amp214zgamp252raybirdi diaquabis4methylaminobenzoatoamp954obisnicotinamideamp954n1cobaltii
AT baramp305amp351tercan diaquabis4methylaminobenzoatoamp954obisnicotinamideamp954n1cobaltii
AT emelermiamp351 diaquabis4methylaminobenzoatoamp954obisnicotinamideamp954n1cobaltii
AT tuncerhamp246kelek diaquabis4methylaminobenzoatoamp954obisnicotinamideamp954n1cobaltii
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