trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate

trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate

In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) a...

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Main Authors: Wade L. Davis, Reinout Meijboom
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812048465
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spelling doaj-fec4d6987f4946d4a1027b3d01d12bd82020-11-25T00:53:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1561m156110.1107/S1600536812048465trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvateWade L. DavisReinout MeijboomIn the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P—Pt—Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148–155].http://scripts.iucr.org/cgi-bin/paper?S1600536812048465
collection DOAJ
language English
format Article
sources DOAJ
author Wade L. Davis
Reinout Meijboom
spellingShingle Wade L. Davis
Reinout Meijboom
trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate
Acta Crystallographica Section E
author_facet Wade L. Davis
Reinout Meijboom
author_sort Wade L. Davis
title trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate
title_short trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate
title_full trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate
title_fullStr trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate
title_full_unstemmed trans-Dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}platinum(II) dichloromethane disolvate
title_sort trans-dichloridobis{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κp}platinum(ii) dichloromethane disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description In the title complex, trans-[PtCl2{P(C6H11)2(4-Me2NC6H4)}2]·2CH2Cl2, the PtII atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P—Pt—Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclohexyl[4-(dimethylamino)phenyl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloromethane solvent molecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148–155].
url http://scripts.iucr.org/cgi-bin/paper?S1600536812048465
work_keys_str_mv AT wadeldavis transdichloridobisdicyclohexyl4dimethylaminophenylphosphaneamp954pplatinumiidichloromethanedisolvate
AT reinoutmeijboom transdichloridobisdicyclohexyl4dimethylaminophenylphosphaneamp954pplatinumiidichloromethanedisolvate
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