Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu Films

VCN–Cu films with different Cu contents were deposited by reactive magnetron sputtering technique. The films were evaluated in terms of their microstructure, elemental composition, mechanical, and tribological properties by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), high re...

Full description

Bibliographic Details
Main Authors: Fanjing Wu, Lihua Yu, Hongbo Ju, Junhua Xu, Ji Shi
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Coatings
Subjects:
Online Access:http://www.mdpi.com/2079-6412/8/3/95
id doaj-ff08b0e22ae345d1ba4be5b62adec65c
record_format Article
spelling doaj-ff08b0e22ae345d1ba4be5b62adec65c2020-11-24T23:58:16ZengMDPI AGCoatings2079-64122018-03-01839510.3390/coatings8030095coatings8030095Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu FilmsFanjing Wu0Lihua Yu1Hongbo Ju2Junhua Xu3Ji Shi4School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaSchool of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaSchool of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaSchool of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaDepartment of Science and Technology, Tokyo Institute of Technology, Tokyo 152-8552, JapanVCN–Cu films with different Cu contents were deposited by reactive magnetron sputtering technique. The films were evaluated in terms of their microstructure, elemental composition, mechanical, and tribological properties by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), high resolution transmission electron microscopy (HR-TEM), Raman spectrometry, nano-indentation, field emission scanning electron microscope (FE-SEM), Bruker three-dimensional (3D) profiler, and high-temperature ball on disc tribo-meter. The results showed that face-centered cubic (fcc) VCN, hexagonal close-packed (hcp) V2CN, fcc-Cu, amorphous graphite and CNx phases co-existed in VCN–Cu films. After doping with 0.6 at.% Cu, the hardness reached a maximum value of ~32 GPa. At room temperature (RT), the friction coefficient and wear rate increased with increasing Cu content. In the temperature range of 100–500 °C, the friction coefficient decreased, but the wear rate increased with the increase of Cu content.http://www.mdpi.com/2079-6412/8/3/95VCN–Cu filmsmicrostructuremechanicalfriction propertywear property
collection DOAJ
language English
format Article
sources DOAJ
author Fanjing Wu
Lihua Yu
Hongbo Ju
Junhua Xu
Ji Shi
spellingShingle Fanjing Wu
Lihua Yu
Hongbo Ju
Junhua Xu
Ji Shi
Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu Films
Coatings
VCN–Cu films
microstructure
mechanical
friction property
wear property
author_facet Fanjing Wu
Lihua Yu
Hongbo Ju
Junhua Xu
Ji Shi
author_sort Fanjing Wu
title Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu Films
title_short Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu Films
title_full Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu Films
title_fullStr Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu Films
title_full_unstemmed Influence of Cu Content on the Structure, Mechanical, Friction and Wear Properties of VCN–Cu Films
title_sort influence of cu content on the structure, mechanical, friction and wear properties of vcn–cu films
publisher MDPI AG
series Coatings
issn 2079-6412
publishDate 2018-03-01
description VCN–Cu films with different Cu contents were deposited by reactive magnetron sputtering technique. The films were evaluated in terms of their microstructure, elemental composition, mechanical, and tribological properties by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), high resolution transmission electron microscopy (HR-TEM), Raman spectrometry, nano-indentation, field emission scanning electron microscope (FE-SEM), Bruker three-dimensional (3D) profiler, and high-temperature ball on disc tribo-meter. The results showed that face-centered cubic (fcc) VCN, hexagonal close-packed (hcp) V2CN, fcc-Cu, amorphous graphite and CNx phases co-existed in VCN–Cu films. After doping with 0.6 at.% Cu, the hardness reached a maximum value of ~32 GPa. At room temperature (RT), the friction coefficient and wear rate increased with increasing Cu content. In the temperature range of 100–500 °C, the friction coefficient decreased, but the wear rate increased with the increase of Cu content.
topic VCN–Cu films
microstructure
mechanical
friction property
wear property
url http://www.mdpi.com/2079-6412/8/3/95
work_keys_str_mv AT fanjingwu influenceofcucontentonthestructuremechanicalfrictionandwearpropertiesofvcncufilms
AT lihuayu influenceofcucontentonthestructuremechanicalfrictionandwearpropertiesofvcncufilms
AT hongboju influenceofcucontentonthestructuremechanicalfrictionandwearpropertiesofvcncufilms
AT junhuaxu influenceofcucontentonthestructuremechanicalfrictionandwearpropertiesofvcncufilms
AT jishi influenceofcucontentonthestructuremechanicalfrictionandwearpropertiesofvcncufilms
_version_ 1725450870198370304