Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
The centrosymmetric binuclear complex, [Cu2(C13H13N2O)2(NCS)2], formed via phenolate oxygen bridges, involves the CuII atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu...Cu separation of 3.2281 (3) Å is obser...
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International Union of Crystallography
2009-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809031742 |
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doaj-ff21f4b0283c42d59dc63476199abc442020-11-25T00:50:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1121m112210.1107/S1600536809031742Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]Gervas E. AsseyYohannes TesemaTeshome YisgeduYilma GultnehRay J. ButcherThe centrosymmetric binuclear complex, [Cu2(C13H13N2O)2(NCS)2], formed via phenolate oxygen bridges, involves the CuII atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu...Cu separation of 3.2281 (3) Å is observed. The in-plane Cu—Ophenolate distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu—Namine and Cu—Npy distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu—Nthiocyanate distance [1.9678 (11) Å] is in the range found for Cu—N distances in previously determined structures containing coordinated thiocyanate anions. There is an intermolecular hydrogen bond between the amine H atom and the S atom of a coordinated thiocyanate anion. http://scripts.iucr.org/cgi-bin/paper?S1600536809031742 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Gervas E. Assey Yohannes Tesema Teshome Yisgedu Yilma Gultneh Ray J. Butcher |
spellingShingle |
Gervas E. Assey Yohannes Tesema Teshome Yisgedu Yilma Gultneh Ray J. Butcher Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)] Acta Crystallographica Section E |
author_facet |
Gervas E. Assey Yohannes Tesema Teshome Yisgedu Yilma Gultneh Ray J. Butcher |
author_sort |
Gervas E. Assey |
title |
Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)] |
title_short |
Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)] |
title_full |
Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)] |
title_fullStr |
Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)] |
title_full_unstemmed |
Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)] |
title_sort |
bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4n,n′,o:o;κ4o:n,n′,o-bis[(thiocyanato-κn)copper(ii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-09-01 |
description |
The centrosymmetric binuclear complex, [Cu2(C13H13N2O)2(NCS)2], formed via phenolate oxygen bridges, involves the CuII atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu...Cu separation of 3.2281 (3) Å is observed. The in-plane Cu—Ophenolate distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu—Namine and Cu—Npy distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu—Nthiocyanate distance [1.9678 (11) Å] is in the range found for Cu—N distances in previously determined structures containing coordinated thiocyanate anions. There is an intermolecular hydrogen bond between the amine H atom and the S atom of a coordinated thiocyanate anion. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809031742 |
work_keys_str_mv |
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