Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]

Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]

The centrosymmetric binuclear complex, [Cu2(C13H13N2O)2(NCS)2], formed via phenolate oxygen bridges, involves the CuII atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu...Cu separation of 3.2281 (3) Å is obser...

Full description

Bibliographic Details
Main Authors: Gervas E. Assey, Yohannes Tesema, Teshome Yisgedu, Yilma Gultneh, Ray J. Butcher
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809031742
id doaj-ff21f4b0283c42d59dc63476199abc44
record_format Article
spelling doaj-ff21f4b0283c42d59dc63476199abc442020-11-25T00:50:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1121m112210.1107/S1600536809031742Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]Gervas E. AsseyYohannes TesemaTeshome YisgeduYilma GultnehRay J. ButcherThe centrosymmetric binuclear complex, [Cu2(C13H13N2O)2(NCS)2], formed via phenolate oxygen bridges, involves the CuII atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu...Cu separation of 3.2281 (3) Å is observed. The in-plane Cu—Ophenolate distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu—Namine and Cu—Npy distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu—Nthiocyanate distance [1.9678 (11) Å] is in the range found for Cu—N distances in previously determined structures containing coordinated thiocyanate anions. There is an intermolecular hydrogen bond between the amine H atom and the S atom of a coordinated thiocyanate anion. http://scripts.iucr.org/cgi-bin/paper?S1600536809031742
collection DOAJ
language English
format Article
sources DOAJ
author Gervas E. Assey
Yohannes Tesema
Teshome Yisgedu
Yilma Gultneh
Ray J. Butcher
spellingShingle Gervas E. Assey
Yohannes Tesema
Teshome Yisgedu
Yilma Gultneh
Ray J. Butcher
Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
Acta Crystallographica Section E
author_facet Gervas E. Assey
Yohannes Tesema
Teshome Yisgedu
Yilma Gultneh
Ray J. Butcher
author_sort Gervas E. Assey
title Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
title_short Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
title_full Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
title_fullStr Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
title_full_unstemmed Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4N,N′,O:O;κ4O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
title_sort bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4n,n′,o:o;κ4o:n,n′,o-bis[(thiocyanato-κn)copper(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description The centrosymmetric binuclear complex, [Cu2(C13H13N2O)2(NCS)2], formed via phenolate oxygen bridges, involves the CuII atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu...Cu separation of 3.2281 (3) Å is observed. The in-plane Cu—Ophenolate distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu—Namine and Cu—Npy distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu—Nthiocyanate distance [1.9678 (11) Å] is in the range found for Cu—N distances in previously determined structures containing coordinated thiocyanate anions. There is an intermolecular hydrogen bond between the amine H atom and the S atom of a coordinated thiocyanate anion.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809031742
work_keys_str_mv AT gervaseassey bisamp95622pyridylmethylaminomethylphenolatoamp9544nnamp8242ooamp9544onnamp8242obisthiocyanatoamp954ncopperii
AT yohannestesema bisamp95622pyridylmethylaminomethylphenolatoamp9544nnamp8242ooamp9544onnamp8242obisthiocyanatoamp954ncopperii
AT teshomeyisgedu bisamp95622pyridylmethylaminomethylphenolatoamp9544nnamp8242ooamp9544onnamp8242obisthiocyanatoamp954ncopperii
AT yilmagultneh bisamp95622pyridylmethylaminomethylphenolatoamp9544nnamp8242ooamp9544onnamp8242obisthiocyanatoamp954ncopperii
AT rayjbutcher bisamp95622pyridylmethylaminomethylphenolatoamp9544nnamp8242ooamp9544onnamp8242obisthiocyanatoamp954ncopperii
_version_ 1725246836287995904

Similar Items