2-(4-Methoxyphenoxy)-3-nitropyridine

In the title molecule, C12H10N2O4, the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO2 [O—N—C—C = &am...

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Bibliographic Details
Main Authors: Shah Bakhtiar Nasir, Zanariah Abdullah, Zainal A. Fairuz, Seik Weng Ng, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810034057
Description
Summary:In the title molecule, C12H10N2O4, the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO2 [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar with their respective aromatic rings. In the crystal, supramolecular layers in the ab plane are formed via C—H...π interactions involving methyl H atoms and the pyridine and benzene rings. Short N—O...π contacts (where the π-system is derived from the pyridine ring) occur between layers in the c-axis direction.
ISSN:1600-5368