Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double Perovskites
Many second phase additions to YBa2Cu3O7−x (YBCO) films, in particular those that self-assemble into aligned nanorod and nanoparticle structures, enhance performance in self and applied fields. Of particular interest for additions are Ba-containing perovskites that are compatible with YBCO. In this...
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doaj-ff870c0ecf00407385048438ca25e7d12020-11-24T23:35:44ZengMDPI AGMaterials1996-19442011-11-014112042205610.3390/ma4112042Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double PerovskitesJavier F. BacaPaul H. TobashPaul D. DowdenYates J. CoulterEric D. BauerLeonardo CivaleBoris MaiorovJohn A. KennisonKenneth R. MarkenTerry G. HolesingerMatthew D. FeldmannMany second phase additions to YBa2Cu3O7−x (YBCO) films, in particular those that self-assemble into aligned nanorod and nanoparticle structures, enhance performance in self and applied fields. Of particular interest for additions are Ba-containing perovskites that are compatible with YBCO. In this report, we discuss the addition of Ba2YRuO6 to bulk and thick-film YBCO. Sub-micron, randomly oriented particles of this phase were found to form around grain boundaries and within YBCO grains in bulk sintered pellets. Within the limits of EDS, no Ru substitution into the YBCO was observed. Thick YBCO films were grown by pulsed laser deposition from a target consisting of YBa2Cu3Oy with 5 and 2.5 mole percent additions of Ba2YRuO6 and Y2O3, respectively. Films with enhanced in-field performance contained aligned, self-assembled Ba2YRuO6 nanorods and strained Y2O3 nanoparticle layers. A 0.9 µm thick film was found to have a self-field critical current density (Jc) of 5.1 MA/cm2 with minimum Jc(Q, H=1T) of 0.75 MA/cm2. Conversely, Jc characteristics were similar to YBCO films without additions when these secondary phases formed as large, disordered phases within the film. A 2.3 µm thick film with such a distribution of secondary phases was found to have reduced self-field Jc values of 3.4 MA/cm2 at 75.5 K and Jc(min, Q, 1T) of 0.4 MA/cm2.http://www.mdpi.com/1996-1944/4/11/2042/superconductivityfilmpulsed laser depositionself-assemblyTEMSTEM |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Javier F. Baca Paul H. Tobash Paul D. Dowden Yates J. Coulter Eric D. Bauer Leonardo Civale Boris Maiorov John A. Kennison Kenneth R. Marken Terry G. Holesinger Matthew D. Feldmann |
spellingShingle |
Javier F. Baca Paul H. Tobash Paul D. Dowden Yates J. Coulter Eric D. Bauer Leonardo Civale Boris Maiorov John A. Kennison Kenneth R. Marken Terry G. Holesinger Matthew D. Feldmann Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double Perovskites Materials superconductivity film pulsed laser deposition self-assembly TEM STEM |
author_facet |
Javier F. Baca Paul H. Tobash Paul D. Dowden Yates J. Coulter Eric D. Bauer Leonardo Civale Boris Maiorov John A. Kennison Kenneth R. Marken Terry G. Holesinger Matthew D. Feldmann |
author_sort |
Javier F. Baca |
title |
Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double Perovskites |
title_short |
Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double Perovskites |
title_full |
Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double Perovskites |
title_fullStr |
Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double Perovskites |
title_full_unstemmed |
Nanorod Self-Assembly in High Jc YBa2Cu3O7−x Films with Ru-Based Double Perovskites |
title_sort |
nanorod self-assembly in high jc yba2cu3o7−x films with ru-based double perovskites |
publisher |
MDPI AG |
series |
Materials |
issn |
1996-1944 |
publishDate |
2011-11-01 |
description |
Many second phase additions to YBa2Cu3O7−x (YBCO) films, in particular those that self-assemble into aligned nanorod and nanoparticle structures, enhance performance in self and applied fields. Of particular interest for additions are Ba-containing perovskites that are compatible with YBCO. In this report, we discuss the addition of Ba2YRuO6 to bulk and thick-film YBCO. Sub-micron, randomly oriented particles of this phase were found to form around grain boundaries and within YBCO grains in bulk sintered pellets. Within the limits of EDS, no Ru substitution into the YBCO was observed. Thick YBCO films were grown by pulsed laser deposition from a target consisting of YBa2Cu3Oy with 5 and 2.5 mole percent additions of Ba2YRuO6 and Y2O3, respectively. Films with enhanced in-field performance contained aligned, self-assembled Ba2YRuO6 nanorods and strained Y2O3 nanoparticle layers. A 0.9 µm thick film was found to have a self-field critical current density (Jc) of 5.1 MA/cm2 with minimum Jc(Q, H=1T) of 0.75 MA/cm2. Conversely, Jc characteristics were similar to YBCO films without additions when these secondary phases formed as large, disordered phases within the film. A 2.3 µm thick film with such a distribution of secondary phases was found to have reduced self-field Jc values of 3.4 MA/cm2 at 75.5 K and Jc(min, Q, 1T) of 0.4 MA/cm2. |
topic |
superconductivity film pulsed laser deposition self-assembly TEM STEM |
url |
http://www.mdpi.com/1996-1944/4/11/2042/ |
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