Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative

p-tert-butylcalix[4]arene was synthesized with the condesation reaction of p-tert-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-...

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Main Authors: E. ERDEM, M. YENIÇERI, Ç. AYDIN, R. MAMMADOV, S. SÖYLEYICI
Format: Article
Language:English
Published: International Journal of Secondary Metabolite 2014-07-01
Series:International Journal of Secondary Metabolite
Subjects:
Online Access:https://dergipark.org.tr/tr/pub/ijsm/issue/22526/240745?publisher=ijate
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spelling doaj-ffce54a50b9b49f289b2a24d35c64d3a2020-11-25T01:44:25ZengInternational Journal of Secondary MetaboliteInternational Journal of Secondary Metabolite2148-69052014-07-0111200618Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy DerivativeE. ERDEM0M. YENIÇERI1Ç. AYDIN2R. MAMMADOV3S. SÖYLEYICI????p-tert-butylcalix[4]arene was synthesized with the condesation reaction of p-tert-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) was synthesized with appropriate pyrrole and aldehyde compounds and then was bonded p-tert-butylcalix[4]arene derivative via lower rim hydroxyl groups.The antioxidant activity of the calix[4]arene-BODIPY compound were determined using β-karotene-linoleic acid system. Moreover, the free radical scavenging activity values were tested with DPPH free radical. The compound showed strong antioxidant activity.Total antioxidant activity of the compound was determined using β–carotenelinoleic acid model system and was found the antioxidant activity of 72,50%. The free radical scavenging activities were determined as 75.19%. Results show that, calix[4]arene-BODIPY compound has the antioxidant activity.https://dergipark.org.tr/tr/pub/ijsm/issue/22526/240745?publisher=ijateantioxidant activity dpph calix[4]arene bodipy calix[4]arene-bodipy derivative
collection DOAJ
language English
format Article
sources DOAJ
author E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
spellingShingle E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
International Journal of Secondary Metabolite
antioxidant activity
dpph
calix[4]arene
bodipy
calix[4]arene-bodipy derivative
author_facet E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
author_sort E. ERDEM
title Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_short Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_full Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_fullStr Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_full_unstemmed Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_sort antioxidant and dpph (1,1-diphenyl-2-picrylhydrazyl) free radical scavenging activities of new the calix[4]arene-bodipy derivative
publisher International Journal of Secondary Metabolite
series International Journal of Secondary Metabolite
issn 2148-6905
publishDate 2014-07-01
description p-tert-butylcalix[4]arene was synthesized with the condesation reaction of p-tert-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) was synthesized with appropriate pyrrole and aldehyde compounds and then was bonded p-tert-butylcalix[4]arene derivative via lower rim hydroxyl groups.The antioxidant activity of the calix[4]arene-BODIPY compound were determined using β-karotene-linoleic acid system. Moreover, the free radical scavenging activity values were tested with DPPH free radical. The compound showed strong antioxidant activity.Total antioxidant activity of the compound was determined using β–carotenelinoleic acid model system and was found the antioxidant activity of 72,50%. The free radical scavenging activities were determined as 75.19%. Results show that, calix[4]arene-BODIPY compound has the antioxidant activity.
topic antioxidant activity
dpph
calix[4]arene
bodipy
calix[4]arene-bodipy derivative
url https://dergipark.org.tr/tr/pub/ijsm/issue/22526/240745?publisher=ijate
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