Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues

Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues

Multinuclear solid-state nuclear magnetic resonance, mass spectrometry, first-principles molecular dynamics simulations, and other complementary evidence reveal that the coordination environment around the Zn2+ ions in MOF-5, one of the most iconic materials among metal-organic frameworks (MOFs), is...

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Bibliographic Details
Main Authors: Bellarosa, Luca (Author), López, Núria (Author), Brozek, Carl Kavanaugh (Contributor), Michaelis, Vladimir K. (Contributor), Ong, Ta-Chung (Contributor), Griffin, Robert Guy (Contributor), Dinca, Mircea (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2016-11-01T16:05:40Z.
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