Gd(iii) and Mn(ii) Complexes for Dynamic Nuclear Polarization: Small Molecular Chelate Polarizing Agents and Applications with Site-Directed Spin Labeling of Proteins

Gd(iii) and Mn(ii) Complexes for Dynamic Nuclear Polarization: Small Molecular Chelate Polarizing Agents and Applications with Site-Directed Spin Labeling of Proteins

We investigate complexes of two paramagnetic metal ions Gd³⁺ and Mn²⁺ to serve as polarizing agents for solid-state dynamic nuclear polarization (DNP) of ¹H, ¹³C, and ¹⁵N at magnetic fields of 5, 9.4, and 14.1 T. Both ions are half-integer high-spin systems with a zero-field splitting and therefore...

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Main Authors: Kaushik, Monu (Author), Bahrenberg, Thorsten (Author), Caporini, Marc A. (Author), Heiliger, Jörg (Author), Schwalbe, Harald (Author), Can, Thach V (Contributor), Silvers, Robert Paul Georg (Contributor), Griffin, Robert Guy (Contributor), Corzilius, Bjorn (Contributor), Silvers, Robert 1968- (Author), Smith, Albert A. (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) (Contributor), Smith, Albert Andrew (Contributor)
Format: Article
Language:English
Published: Royal Society of Chemistry (RSC), 2018-01-29T16:34:38Z.
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