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|a Xu, B.
|e author
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|a Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
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|a Massachusetts Institute of Technology. Department of Materials Science and Engineering
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|a Li, Huashan
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|a Grossman, Jeffrey C.
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|a Hall, A.
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|a Gao, W.
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|a Gong, M.
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|a Yuan, G.
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|a Ren, S.
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|a Li, Huashan
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|a Grossman, Jeffrey C.
|e author
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|a All-polymeric control of nanoferronics
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|b American Association for the Advancement of Science (AAAS),
|c 2018-05-17T18:13:18Z.
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|z Get fulltext
|u http://hdl.handle.net/1721.1/115433
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|a In the search for light and flexible nanoferronics, significant research effort is geared toward discovering the coexisting magnetic and electric orders in crystalline charge-transfer complexes. We report the first example of multiferroicity in centimeter-sized crystalline polymeric charge-transfer superstructures that grow at the liquidair interface and are controlled by the regioregularity of the polymeric chain. The charge order-driven ferroic mechanism reveals spontaneous and hysteretic polarization and magnetization at the donor-acceptor interface. The charge transfer and ordering in the ferroic assemblies depend critically on the self-organizing and molecular packing of electron donors and acceptors. The invention described here not only represents a new coupling mechanism of magnetic and electric ordering but also creates a new class of emerging all-organic nanoferronics. Keywords: self-assembly; crystalline structures; magnetoelectrics; charge transfer
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|a Article
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|t Science Advances
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