Biphilic Organophosphorus-Catalyzed Intramolecular C[subscript sp2]-H Amination: Evidence for a Nitrenoid in Catalytic Cadogan Cyclizations
A small-ring phosphacycloalkane (1,2,2,3,4,4-hexamethylphosphetane, 3) catalyzes intramolecular C-N bond forming heterocyclization of o-nitrobiaryl and -styrenyl derivatives in the presence of a hydrosilane terminal reductant. The method provides scalable access to diverse carbazole and indole compo...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS),
2020-01-14T18:33:10Z.
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| Subjects: | |
| Online Access: | Get fulltext |