Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks

Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks

Reaction of 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and 2,3,6,7,10,11-hexaaminotriphenylene (HATP) with [Cu(Me3tacn)]2+ (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) produces trigonal tricopper complexes [(Me3tacnCu)3(HOTP)]3+ (1) and [(Me3tacnCu)3(HITP)]4+ (2) (HOTP, HITP = hexaoxy- and...

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Bibliographic Details
Main Authors: Yang, Luming (Author), He, Xin (Author), Dinca, Mircea (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2020-10-26T19:47:25Z.
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