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|a Voll, Constantin-Chri Alexander
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|a Massachusetts Institute of Technology. Department of Chemistry
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|a Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
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|a Markopoulos, Georgios
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|a Wu, Tony C
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|a Welborn, Matthew Gregory
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|a Engelhart, Jens
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|a Rochat, Sebastien
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|a Han, Ggoch Ddeul
|q (Ggoch Ddeul Grace)
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|a Sazama, Graham T.
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|a Lin, Ting-An
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|a Van Voorhis, Troy
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|a Baldo, Marc A
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|a Swager, Timothy M
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|a Lock-and-Key Exciplexes for Thermally Activated Delayed Fluorescence
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|b Georg Thieme Verlag KG,
|c 2020-12-08T15:42:58Z.
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|z Get fulltext
|u https://hdl.handle.net/1721.1/128745
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|a We combine synthetic supramolecular chemistry and materials science to develop novel exciplexes for thermally activated delayed fluorescence. Our approach starts from a bowl-shaped acceptor molecule for which we synthesize tailor-made donors that bind in a lock-and-key fashion. The donor design is guided by extensive density functional theory calculations of three independent donor families. The investigation of a large number of custom-synthesized donors allows us to derive empirical relationships for the prediction of the exciplex emission color. Incorporated within organic light-emitting devices, the lock-and-key exciplexes yield external quantum efficiencies of up to 5.4%, with potentially tunable emission color across the blue and green visible spectrum.
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|a Air Force Office of Scientific Research (Grant FA9550-18-1-0341)
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|a Department of Energy (Grant DE-FG02-07ER46474)
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|a NIH (Grant GM112272)
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|a en
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|a Article
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|t Organic Materials
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