Validating the Biphilic Hypothesis of Nontrigonal Phosphorus(III) Compounds
Constraining σ3-P compounds in nontrigonal, entatic geometries has proven to be an effective strategy for promoting biphilic oxidative addition reactions more typical of transition metals. Although qualitative descriptions of the impact of structure and symmetry on σ3-P complexes have been proposed,...
Main Authors: | Lee, Kyounghoon (Author), Blake, Anastasia V. (Author), Tanushi, Akira (Author), McCarthy, Sean M. (Author), Kim, Daniel (Author), Loria, Sydney M. (Author), Donahue, Courtney M. (Author), Spielvogel, Kyle D. (Author), Keith, Jason M. (Author), Daly, Scott R. (Author), Radosevich, Alexander T. (Author) |
---|---|
Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor) |
Format: | Article |
Language: | English |
Published: |
Wiley,
2021-02-05T22:18:13Z.
|
Subjects: | |
Online Access: | Get fulltext |
Similar Items
-
Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane
by: Tanushi, Akira, et al.
Published: (2020) -
Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes
by: Lin, Yi-Chun, et al.
Published: (2020) -
Bond activation and catalysis by nontrigonal tricoordinate and tetracoordinate phosphorus compounds
by: Lin, Yi-Chun, Ph. D. Massachusetts Institute of Technology
Published: (2018) -
Enthalpy-Controlled Insertion of a "Nonspectator" Tricoordinate Phosphorus Ligand into Group 10 Transition Metal-Carbon Bonds
by: Hwang, Seung Jun, et al.
Published: (2022) -
Enthalpy-Controlled Insertion of a "Nonspectator" Tricoordinate Phosphorus Ligand into Group 10 Transition Metal-Carbon Bonds
by: Hwang, Seung Jun, et al.
Published: (2022)