Gradient-morph LiCoO2 single crystals with stabilized energy density above 3400 W h L−1
The cycling stability of LiCoO[subscript 2] under high voltages (>4.5 V) was plagued by hybrid anion- and cation-redox (HACR) induced oxygen escape and uncontrolled phase collapse. With DEMS and in situ XANES mapping at the NSLS-II, we demonstrate that oxygen escape triggers irreversible transfor...
Main Authors: | Zhu, Zhi (Author), Yu, Daiwei (Author), Shi, Zhe (Author), Gao, Rui (Author), Xiao, Xianghui (Author), Waluyo, Iradwikanari (Author), Ge, Mingyuan (Author), Dong, Yanhao (Author), Xue, Weijiang (Author), Xu, Guiyin (Author), Lee, Wah-Keat (Author), Hunt, Adrian (Author), Li, Ju (Author) |
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Other Authors: | Massachusetts Institute of Technology. Department of Nuclear Science and Engineering (Contributor), Massachusetts Institute of Technology. Department of Materials Science and Engineering (Contributor), Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science (Contributor) |
Format: | Article |
Language: | English |
Published: |
Royal Society of Chemistry (RSC),
2021-09-22T14:21:19Z.
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Subjects: | |
Online Access: | Get fulltext |
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