|
|
|
|
| LEADER |
01815 am a22003013u 4500 |
| 001 |
58625 |
| 042 |
|
|
|a dc
|
| 100 |
1 |
0 |
|a Emelianova, E.V.
|e author
|
| 100 |
1 |
0 |
|a Massachusetts Institute of Technology. Department of Chemistry
|e contributor
|
| 100 |
1 |
0 |
|a Silbey, Robert J.
|e contributor
|
| 100 |
1 |
0 |
|a Silbey, Robert J.
|e contributor
|
| 700 |
1 |
0 |
|a Athanasopoulos, S.
|e author
|
| 700 |
1 |
0 |
|a Silbey, Robert J.
|e author
|
| 700 |
1 |
0 |
|a Beljonne, D.
|e author
|
| 245 |
0 |
0 |
|a 2D Excitons as Primary Energy Carriers in Organic Crystals: The Case of Oligoacenes
|
| 260 |
|
|
|b American Physical Society,
|c 2010-09-21T16:52:09Z.
|
| 856 |
|
|
|z Get fulltext
|u http://hdl.handle.net/1721.1/58625
|
| 520 |
|
|
|a A number of organic crystals show anisotropic excitonic couplings, with weak interlayer interactions between molecules that are more strongly coupled within the layers. The resulting energy carriers are intralayer 2D excitons that diffuse along the interlayer direction. We model this analytically for infinite layers and using quantum-chemical calculations of the electronic couplings for anthracene clusters. We show that the exciton hopping rates and diffusion lengths depend in a subtle manner on the size and shape of the interacting aggregates, temperature, and the presence of energetic disorder.
|
| 520 |
|
|
|a European Union. MODECOM (NMP3-CT-2006-016434)
|
| 520 |
|
|
|a European Union. ONE-P (NMP3-LA-2008-212311)
|
| 520 |
|
|
|a Fonds national de la recherche scientifique (Belgium)
|
| 520 |
|
|
|a The Inter University Computation Center (Israel)
|
| 520 |
|
|
|a United States. Dept. of Energy. Office of Science
|
| 520 |
|
|
|a United States. Dept. of Energy. Office of Basic Energy
|
| 520 |
|
|
|a United States. Dept. of Energy (Grant No DE-SC0001088)
|
| 546 |
|
|
|a en_US
|
| 655 |
7 |
|
|a Article
|
| 773 |
|
|
|t Physical Review Letters
|
