Diffuse-charge effects on the transient response of electrochemical cells
We present theoretical models for the time-dependent voltage of an electrochemical cell in response to a current step, including effects of diffuse charge (or "space charge") near the electrodes on Faradaic reaction kinetics. The full model is based on the classical Poisson-Nernst-Planck e...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Physical Society,
2010-09-29T12:52:25Z.
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| Subjects: | |
| Online Access: | Get fulltext |